{"id":"W2950127372","doi":"10.1139/v05-134","title":"A mild and efficient procedure for the conversion of aromatic carboxylic esters to secondary amides","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Microwave-Assisted Synthesis and Applications","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Dimethylformamide; Primary (astronomy); Organic chemistry; Carboxylic acid; Solvent; Distilled water; Chromatography","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000120943,0.00009666789,0.0001655449,0.00002995178,0.0001076987,0.00002785154,0.0002189859,0.00007015241,0.0002543176],"category_scores_gemma":[0.0000936537,0.00007560561,0.00008628992,0.00006139956,0.00008555092,0.00002124517,0.000009272765,0.0001337803,9.890522e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009892732,"about_ca_system_score_gemma":0.0005571399,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008708034,"about_ca_topic_score_gemma":0.0002200626,"domain_scores_codex":[0.999351,0.000003045295,0.0002935689,0.0001010575,0.00008572642,0.0001656336],"domain_scores_gemma":[0.999095,0.0001212414,0.0002036544,0.0001693527,0.00007837483,0.0003324367],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001938893,0.00002155923,0.0003650203,0.0006843656,0.00007642517,0.000002479191,0.0008597735,0.0002201379,0.9872554,0.000005343579,0.005509579,0.00498052],"study_design_scores_gemma":[0.0003540028,0.000008931498,0.0004232058,0.0002778287,0.00006770366,0.0001064593,0.001464074,0.0003376886,0.9709412,0.00001258484,0.0258972,0.000109067],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947959,0.001180511,0.00004261856,0.002088191,0.00001536046,0.00007319413,0.00005766621,0.000002568471,0.001743948],"genre_scores_gemma":[0.9990174,0.00001174733,0.0003541706,0.000157808,0.000112046,0.000009836715,0.000002631258,0.00001202929,0.0003222938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02038762,"threshold_uncertainty_score":0.3083107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009369168206951306,"score_gpt":0.2064987258223618,"score_spread":0.1971295576154105,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}