{"id":"W2950127662","doi":"10.1021/ol052086c","title":"A Domino Amidation Route to Indolines and Indoles:  Rapid Syntheses of Anhydrolycorinone, Hippadine, Oxoassoanine, and Pratosine","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":92,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Domino; Aryl; Combinatorial chemistry; Palladium; Catalysis; Amination; Indole test; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001168118,0.0004148936,0.0002238885,0.0002151643,0.0002153484,0.0001711607,0.0004944408,0.0002319729,0.001526964],"category_scores_gemma":[0.0001119703,0.0001642252,0.0001667531,0.0001922759,0.0002545563,0.0003588907,0.0004181997,0.0005383516,0.0006147596],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002360703,"about_ca_system_score_gemma":0.0003021628,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004143675,"about_ca_topic_score_gemma":0.001227527,"domain_scores_codex":[0.9999056,0.00001149151,0.00000673459,0.00002684913,0.00002754094,0.00002185164],"domain_scores_gemma":[0.9999486,0.000007173495,0.00001650378,0.000006992535,0.000006827277,0.00001400746],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007124147,0.0000462602,0.0001051166,0.00016688,0.00001429446,0.0003449982,0.0001124353,0.0002225979,0.9828035,0.001209125,0.000328614,0.01457497],"study_design_scores_gemma":[0.00005419454,0.0007010198,0.001130039,0.00001532369,0.00001821036,0.001392097,0.00003852531,0.0007071527,0.9713143,0.0004242792,0.02418428,0.00002068678],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8656139,0.01264563,0.07928759,0.0005409668,0.0002633019,0.0004921061,0.000824139,0.0009173345,0.03941502],"genre_scores_gemma":[0.9628293,0.004981643,0.02297804,0.0001237998,0.00004982213,0.0001219454,0.0003764317,0.00005893733,0.008480047],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001526964,"threshold_uncertainty_score":0.005108178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007935959644549587,"score_gpt":0.202622411571865,"score_spread":0.1946864519273154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}