{"id":"W2950164171","doi":"10.1002/chin.201003057","title":"ChemInform Abstract: Development of a Palladium Catalyzed Addition of Boronic Acids to Alkynyl Esters: Synthesis of Trisubstituted Olefins as Single Isomers.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Combinatorial chemistry; Palladium; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003942359,0.00044145,0.0008775974,0.0001424731,0.00005031508,0.00001650967,0.0006751593,0.0004042391,0.004675282],"category_scores_gemma":[0.001354943,0.0004655737,0.0002541711,0.0004386556,0.0001721142,0.0002149671,0.0001207276,0.0002066006,0.00003026848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004980924,"about_ca_system_score_gemma":0.0006028085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002399161,"about_ca_topic_score_gemma":0.000005515572,"domain_scores_codex":[0.9968383,2.62182e-7,0.001609209,0.0003842777,0.0006550531,0.0005129103],"domain_scores_gemma":[0.9972519,0.0003314779,0.0009691663,0.000913439,0.0002678121,0.0002661492],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001508367,0.0002653431,0.000007373015,0.000634983,0.00009906039,0.000001996198,0.001599873,4.839842e-7,0.698566,0.000009296776,0.0004079763,0.2982568],"study_design_scores_gemma":[0.0008447623,0.00003801293,0.0003305768,0.0007739335,0.0001142976,0.0000258254,0.00115416,0.000002016723,0.9902337,0.00003081627,0.006017726,0.0004342211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.594902,0.00008615055,0.000007725428,0.00006955484,0.00005444907,0.0001796304,0.0001514161,0.00008247807,0.4044666],"genre_scores_gemma":[0.9934622,0.00002075967,0.004568244,0.00002888405,0.00006528092,0.00003876511,0.0002111198,0.0000377306,0.001567027],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4028996,"threshold_uncertainty_score":0.9997796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01942284206235557,"score_gpt":0.2615097094823029,"score_spread":0.2420868674199473,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}