{"id":"W2950169099","doi":"10.1139/v00-015","title":"Preparation of homoallylic alcohols by reaction of aldehydes with η<sup>3</sup>-allyl- and η<sup>3</sup>-crotylmolybdenum complexes","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Molybdenum; Chelation; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002716428,0.0002843329,0.0006334282,0.0001365099,0.0001163231,0.00005979265,0.0003698842,0.0002421445,0.001729946],"category_scores_gemma":[0.0001338362,0.0002653518,0.0001928584,0.0003399716,0.0003155126,0.0002577049,0.00001279731,0.0002992464,0.00000307685],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001695604,"about_ca_system_score_gemma":0.0006066068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002019569,"about_ca_topic_score_gemma":0.0002034744,"domain_scores_codex":[0.9980638,0.00002602645,0.0008331842,0.0002850691,0.0004385625,0.0003533376],"domain_scores_gemma":[0.9979206,0.0001224081,0.000678233,0.0004194088,0.0003017823,0.000557569],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00059683,0.0002912261,0.013951,0.001043718,0.001304133,0.0001237894,0.002810247,0.001963182,0.9077103,0.00001188695,0.01278027,0.05741346],"study_design_scores_gemma":[0.0009936016,0.00008982659,0.0005186805,0.0003966925,0.0002767782,0.0005878311,0.00182887,0.0003281944,0.9836891,0.00004521841,0.01090288,0.0003422782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9802864,0.001667581,0.00001800762,0.0001432361,0.000006747232,0.00005709237,0.0001905135,0.000009030949,0.01762138],"genre_scores_gemma":[0.997268,0.0001737087,0.0001980865,0.0000283896,0.0001574449,0.000005239507,0.00007325414,0.00003662061,0.002059258],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0759789,"threshold_uncertainty_score":0.9999799,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007504015656557851,"score_gpt":0.2162887376513733,"score_spread":0.2087847219948154,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}