{"id":"W2950176050","doi":"10.1007/s007060170084","title":"Efficient Routes to ω-Chloroalkyl Bilirubins and C12-N22 Bridged Biliverdins","year":2001,"lang":"en","type":"article","venue":"Monatshefte für Chemie - Chemical Monthly","topic":"Heme Oxygenase-1 and Carbon Monoxide","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia","funders":"National Natural Science Foundation of China","keywords":"Sodium borohydride; Sodium hydroxide; Chemistry; Ethanol; Sodium; Nuclear chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000238806,0.0005220384,0.0004520441,0.00009412932,0.0001221183,0.00007036448,0.0004512374,0.0004108032,0.00006816433],"category_scores_gemma":[0.0003532591,0.0005090986,0.0002419485,0.000321333,0.0001845109,0.000006953793,0.0005120794,0.0002799396,0.0000536907],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001016619,"about_ca_system_score_gemma":0.00007638783,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001315613,"about_ca_topic_score_gemma":0.00003446027,"domain_scores_codex":[0.9970619,0.0000366072,0.0005049845,0.001179119,0.0003907364,0.0008266511],"domain_scores_gemma":[0.998212,0.00004862924,0.0001028323,0.0008000427,0.0001374051,0.0006991199],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002408501,0.0002176113,0.00304603,0.00002772573,0.00007188623,0.00004032622,0.0001041779,0.0002919168,0.9883673,0.00002145374,0.004901177,0.002669518],"study_design_scores_gemma":[0.0009531304,0.0001550381,0.003120875,0.00003066342,0.00004423615,0.00003565223,0.00009319941,0.000677734,0.9467209,0.00005385881,0.04744756,0.0006671818],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899214,0.001494152,0.0001451294,0.0008534067,0.0001317508,0.0004157306,0.00008776563,0.00009858509,0.006852095],"genre_scores_gemma":[0.9955917,0.000135548,0.0009052206,0.001229187,0.0004375982,0.0001094371,0.000194092,0.00008626603,0.001310939],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04254638,"threshold_uncertainty_score":0.9997361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007625239408011556,"score_gpt":0.2395668911357093,"score_spread":0.2319416517276978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}