{"id":"W2950207813","doi":"10.1021/ol1003669","title":"Tandem Phenolic Oxidative Amidation−Intramolecular Diels−Alder Reaction: An Approach to the Himandrine Core","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research","keywords":"Chemistry; Iodobenzene; Intramolecular force; Tandem; Desymmetrization; Oxidative phosphorylation; Diels–Alder reaction; Organic chemistry; Stereochemistry; Catalysis; Enantioselective synthesis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002070272,0.0005410229,0.0002381733,0.0002169077,0.0002565692,0.0002937524,0.0003597385,0.0003191513,0.00135657],"category_scores_gemma":[0.00008059572,0.0001717688,0.0002318132,0.0001991036,0.0002189774,0.0003732611,0.0004118907,0.0005082214,0.0008319637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002784294,"about_ca_system_score_gemma":0.0003407989,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002569033,"about_ca_topic_score_gemma":0.0008625917,"domain_scores_codex":[0.9998966,0.00002023323,0.000006700243,0.00002598747,0.00001610143,0.00003440345],"domain_scores_gemma":[0.9999495,0.000005149897,0.00001352015,0.00001435967,0.000005300972,0.00001227551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009294942,0.00008092816,0.0001289558,0.0001414611,0.00001801467,0.0002981951,0.00008834953,0.0002825455,0.9810884,0.002088407,0.0001825128,0.01550918],"study_design_scores_gemma":[0.00001145701,0.0002767311,0.0003539211,0.000003986679,0.0000142234,0.0002636847,0.00001772254,0.0003509449,0.9914882,0.0001704738,0.007039757,0.000008971809],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9227372,0.003941083,0.05059939,0.0003478077,0.0001600643,0.0001956287,0.0003671273,0.0004306662,0.02122101],"genre_scores_gemma":[0.9741468,0.002053516,0.01544556,0.00006948857,0.000044713,0.00004722693,0.0001973536,0.0000305466,0.007964857],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00135657,"threshold_uncertainty_score":0.004538178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01257775335459506,"score_gpt":0.2188808212417762,"score_spread":0.2063030678871812,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}