{"id":"W2950221685","doi":"10.1002/chin.201422205","title":"ChemInform Abstract: Studies on Difficult Intramolecular Hydroaminations in the Context of Four Syntheses of Alkaloid Natural Products.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Hydroamination; Intramolecular force; Ring (chemistry); Context (archaeology); Alkaloid; Stereochemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003066634,0.0002723029,0.0004089161,0.00006117023,0.00006287886,0.00001615078,0.0005011449,0.0001309847,0.0001597341],"category_scores_gemma":[0.00518163,0.0001988651,0.000110692,0.0003588427,0.0003569965,0.0001195174,0.0000824933,0.0004038778,0.00001187994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001584965,"about_ca_system_score_gemma":0.0000759599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000163986,"about_ca_topic_score_gemma":0.00001656735,"domain_scores_codex":[0.9983784,3.222805e-7,0.00068268,0.000248514,0.000430668,0.0002593901],"domain_scores_gemma":[0.9976088,0.0008055419,0.0005055785,0.0006601618,0.0003811281,0.00003878898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003353358,0.0002719206,0.00003504532,0.0009104072,0.0001399327,0.000002483655,0.004916951,0.000001051757,0.9295626,0.000674642,0.001773724,0.06167774],"study_design_scores_gemma":[0.000353331,0.00002073791,0.0002948675,0.0002790317,0.00004192203,0.00002010905,0.01111174,0.00001819336,0.9840935,0.00004212604,0.003527161,0.000197227],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5359977,0.0001383709,5.008635e-8,0.0003934606,0.00005739425,0.0001321937,0.00003458592,0.00003186573,0.4632144],"genre_scores_gemma":[0.9964621,0.00003569002,0.00001586332,0.00005751058,0.00009711299,0.00004951877,0.00005857343,0.00002011638,0.003203533],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4604644,"threshold_uncertainty_score":0.8109484,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02141569120992043,"score_gpt":0.2544758852628619,"score_spread":0.2330601940529414,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}