{"id":"W2950221842","doi":"10.1002/chin.201022092","title":"ChemInform Abstract: Unique Diastereoselectivity Trends in Aminyl Radical Cyclizations onto Silyl Enol Ethers.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Silylation; Enol; Service (business); Photochemistry; Combinatorial chemistry; Organic chemistry; World Wide Web; Catalysis; Business; Computer science; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005588437,0.0008315539,0.0002146872,0.0005330337,0.0002533722,0.0005523491,0.0004206973,0.0003645883,0.01196235],"category_scores_gemma":[0.0004507756,0.0002304505,0.0002237139,0.0004347629,0.0002948559,0.00106014,0.0003402705,0.0009810892,0.003117867],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000292912,"about_ca_system_score_gemma":0.0003326433,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002803245,"about_ca_topic_score_gemma":0.0008129145,"domain_scores_codex":[0.9997537,0.00003746538,0.00001470422,0.00004841343,0.00006440812,0.00008149134],"domain_scores_gemma":[0.9998786,0.00003637484,0.00002509783,0.00001458011,0.0000204698,0.00002476481],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0008600965,0.0002282251,0.0002563575,0.0007191023,0.00005952762,0.0004198699,0.0002962901,0.0005871693,0.9191709,0.006848305,0.01015345,0.06040077],"study_design_scores_gemma":[0.00003448931,0.0004940237,0.0005140073,0.00002473044,0.00003164422,0.0002669061,0.00004093365,0.000448435,0.9746106,0.0005160657,0.02299369,0.00002457156],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.7474954,0.01522678,0.03417923,0.00160573,0.001394794,0.0003439608,0.003708075,0.002001005,0.1940451],"genre_scores_gemma":[0.9510733,0.009199963,0.007314872,0.0003471297,0.0001835411,0.00007642444,0.001759643,0.0003230663,0.02972201],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.01196235,"threshold_uncertainty_score":0.04001808,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01263076729294762,"score_gpt":0.2663721032966885,"score_spread":0.2537413360037409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}