{"id":"W2950230361","doi":"10.1002/chin.201551045","title":"ChemInform Abstract: The Selective Cross‐Coupling of Secondary Alkyl Zinc Reagents to Five‐Membered‐Ring Heterocycles Using Pd‐PEPPSI‐IHept<sup>Cl</sup>.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Ring (chemistry); Reagent; Alkyl; Alkylation; Zinc; Catalysis; Medicinal chemistry; Coupling (piping); Combinatorial chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005531965,0.0005934018,0.0006291979,0.0001487146,0.0004284579,0.0003519354,0.0009645236,0.0004216157,0.000865477],"category_scores_gemma":[0.00070899,0.0005451037,0.0003474914,0.000465776,0.0003892592,0.0008459234,0.0006116824,0.0008844315,0.0001427396],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001154856,"about_ca_system_score_gemma":0.0005831281,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006331368,"about_ca_topic_score_gemma":0.00003795394,"domain_scores_codex":[0.9964296,2.526736e-8,0.001189525,0.000609679,0.0008490022,0.0009222222],"domain_scores_gemma":[0.9967411,0.0003144309,0.0006336931,0.001184855,0.0006178084,0.0005081128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007943674,0.0004448152,0.002738954,0.001632523,0.0009763912,0.00004835774,0.03223628,0.01624895,0.8490744,0.00005021908,0.01680274,0.07895195],"study_design_scores_gemma":[0.001265477,0.00002166291,0.0005064179,0.0002928798,0.000104981,0.0001498485,0.004987903,0.005104328,0.9794722,0.0000669373,0.007411321,0.0006160657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8096187,0.0001159053,9.806776e-7,0.00003572395,0.0001480749,0.0002575562,0.0001525984,0.0001700461,0.1895005],"genre_scores_gemma":[0.9878928,0.00001160705,0.00004931474,0.00008912893,0.0004604231,0.00004231612,0.000183549,0.0001014473,0.01116943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.178331,"threshold_uncertainty_score":0.9997001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03374443131425196,"score_gpt":0.302357980581312,"score_spread":0.26861354926706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}