{"id":"W2950260617","doi":"10.1021/ic000988y","title":"Synthesis and Reactivity of Perhalogenated Acyclic and Metallacyclic Tantalum(V) Phosphoraniminato Complexes:  Discovery of an Unexpected Ligand Coupling Reaction To Form the Novel Phosphazenium Salt [N(PCl<sub>2</sub>NH<sub>2</sub>)<sub>2</sub>][TaCl<sub>6</sub>]","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Protonolysis; Ligand (biochemistry); Tantalum; Yield (engineering); Reactivity (psychology); Octahedron; Medicinal chemistry; Salt (chemistry); Molecule; Coupling reaction; Crystal structure; Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.00100273,0.001648495,0.002445773,0.0002866288,0.0007651852,0.0003704864,0.001269505,0.0009289405,0.0001065287],"category_scores_gemma":[0.001197807,0.001579764,0.0007125366,0.001941801,0.0008647353,0.001071639,0.0009341001,0.00111461,0.00002134942],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007495066,"about_ca_system_score_gemma":0.0003780238,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003299286,"about_ca_topic_score_gemma":0.0004006341,"domain_scores_codex":[0.9923997,0.00009618182,0.002237054,0.002373385,0.00143574,0.001457925],"domain_scores_gemma":[0.9931613,0.001327316,0.001770795,0.002445754,0.0005389614,0.0007558353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007794542,0.00145096,0.0009702241,0.000930514,0.001137608,0.00005084128,0.000816214,0.00001419794,0.9817898,0.00001331985,0.0000403513,0.01200651],"study_design_scores_gemma":[0.001724971,0.0001090292,0.007024445,0.0005106921,0.001725657,0.0006105434,0.00240566,0.0006758306,0.9833637,0.00009693741,0.0001359859,0.00161658],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960038,0.001532166,0.0001042431,0.0002710492,0.0001443323,0.0006711524,0.0006664342,0.000323844,0.0002829891],"genre_scores_gemma":[0.995455,0.003108436,0.00003852057,0.00008235468,0.0003764517,0.0001676757,0.0003801453,0.0003648331,0.00002653278],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01038993,"threshold_uncertainty_score":0.9996262,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0109275420788333,"score_gpt":0.2154658479581864,"score_spread":0.2045383058793531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}