{"id":"W2950260617","doi":"10.1021/ic000988y","title":"Synthesis and Reactivity of Perhalogenated Acyclic and Metallacyclic Tantalum(V) Phosphoraniminato Complexes:  Discovery of an Unexpected Ligand Coupling Reaction To Form the Novel Phosphazenium Salt [N(PCl<sub>2</sub>NH<sub>2</sub>)<sub>2</sub>][TaCl<sub>6</sub>]","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Protonolysis; Ligand (biochemistry); Tantalum; Yield (engineering); Reactivity (psychology); Octahedron; Medicinal chemistry; Salt (chemistry); Molecule; Coupling reaction; Crystal structure; Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007952173,0.0001777616,0.0001180217,0.0001219944,0.0001358289,0.000297651,0.0003756498,0.000214857,0.0009134819],"category_scores_gemma":[0.00018768,0.0001015195,0.0001158663,0.0001645729,0.0001913537,0.0002107839,0.0002181955,0.0002328673,0.0002752117],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004774061,"about_ca_system_score_gemma":0.0001785282,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000799867,"about_ca_topic_score_gemma":0.002020451,"domain_scores_codex":[0.9999173,0.00001011628,0.000007139896,0.00002099557,0.00002531446,0.00001917871],"domain_scores_gemma":[0.999944,0.00000646424,0.00001690011,0.000009699679,0.000009807579,0.00001318707],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008903267,0.00001376862,0.0002648359,0.00006315078,0.000008258095,0.00009102571,0.00006482375,0.0002609382,0.9953251,0.0003769442,0.00005831704,0.003383801],"study_design_scores_gemma":[0.00001110282,0.0001461314,0.0006287579,0.000002325903,0.000008959927,0.0001929358,0.00002717334,0.0004883682,0.9958192,0.00004054317,0.002628893,0.000005543352],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944683,0.0005263872,0.001616006,0.00004272315,0.00000802487,0.00001873586,0.0001184811,0.00006915322,0.00313203],"genre_scores_gemma":[0.9959974,0.0002460269,0.001937411,0.00001677099,0.000002427621,0.00001089896,0.0001738886,0.0000158458,0.001599319],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009134819,"threshold_uncertainty_score":0.003463805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0109275420788333,"score_gpt":0.2154658479581864,"score_spread":0.2045383058793531,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}