{"id":"W2950262782","doi":"10.1002/chin.201139035","title":"ChemInform Abstract: Efficient and Controllably Selective Preparation of Esters Using Uronium‐Based Coupling Agents.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Reagent; Primary (astronomy); Coupling (piping); Tertiary alcohols; Base (topology); Organic chemistry; Combinatorial chemistry; Alcohol","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001281653,0.0001451789,0.0001955561,0.00003373155,0.00004665182,0.00001321399,0.00009399759,0.0001298246,0.00008024068],"category_scores_gemma":[0.00006901245,0.0001330754,0.0001044284,0.00008599935,0.00008773412,0.000006781699,0.00004625836,0.00005132508,0.000001318903],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003203577,"about_ca_system_score_gemma":0.00006559902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004062288,"about_ca_topic_score_gemma":0.000004304277,"domain_scores_codex":[0.9991885,8.15871e-8,0.0003025532,0.0002026431,0.0001211794,0.0001850445],"domain_scores_gemma":[0.9994032,0.00001435059,0.0002122349,0.0001829628,0.0001073544,0.0000799272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002670469,0.00009242761,0.0004612612,0.00008064278,0.0001221885,5.918891e-7,0.0002935529,0.00012328,0.9851382,0.000008388944,0.000244398,0.01316805],"study_design_scores_gemma":[0.000494341,0.00005224171,0.0005624745,0.00002420606,0.00007231312,0.000002209506,0.0001210035,0.004633343,0.9931798,0.000003159215,0.0007005752,0.0001543203],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9333979,0.0001886724,0.00002287497,0.000004858143,0.00001850984,0.0001301249,0.00001029962,0.00000840653,0.06621834],"genre_scores_gemma":[0.9994165,0.00002081267,0.000140316,0.00004429172,0.00003411373,0.000008463849,0.0000477386,0.00001113669,0.0002765869],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06601863,"threshold_uncertainty_score":0.5426657,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01944396976510279,"score_gpt":0.2585374391086168,"score_spread":0.239093469343514,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}