{"id":"W2950262782","doi":"10.1002/chin.201139035","title":"ChemInform Abstract: Efficient and Controllably Selective Preparation of Esters Using Uronium‐Based Coupling Agents.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Chemistry; Reagent; Primary (astronomy); Coupling (piping); Tertiary alcohols; Base (topology); Organic chemistry; Combinatorial chemistry; Alcohol","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003281488,0.0008205188,0.0002628837,0.0007151895,0.0002933795,0.000362439,0.0005223488,0.0003716406,0.008220179],"category_scores_gemma":[0.0003025615,0.0004086792,0.000169263,0.0004601844,0.0002228532,0.0005906778,0.0005167843,0.0005236207,0.004946697],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003812828,"about_ca_system_score_gemma":0.0005824657,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004085403,"about_ca_topic_score_gemma":0.0009464338,"domain_scores_codex":[0.999846,0.00002981521,0.00001009113,0.00003047392,0.00005256902,0.00003095712],"domain_scores_gemma":[0.999922,0.00001460201,0.0000203961,0.000009657727,0.00001534407,0.00001791472],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003906448,0.00007370426,0.0002159725,0.0006409803,0.00002991202,0.000206787,0.00004769518,0.0003847734,0.9336092,0.002496737,0.005969963,0.05593361],"study_design_scores_gemma":[0.00002507729,0.0000523649,0.0002359469,0.00002008618,0.00001364704,0.0001487814,0.000006775206,0.0003230447,0.9780227,0.00009903526,0.02104238,0.00001021654],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5165783,0.02463808,0.2233038,0.001622902,0.0008232098,0.001036371,0.007689667,0.006727049,0.2175806],"genre_scores_gemma":[0.7868322,0.02073936,0.1080248,0.000864663,0.0001646061,0.0005364894,0.006448522,0.0007419818,0.07564735],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008220179,"threshold_uncertainty_score":0.0274992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01944396976510279,"score_gpt":0.2585374391086168,"score_spread":0.239093469343514,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}