{"id":"W2950288815","doi":"10.1002/chin.201001067","title":"ChemInform Abstract: Practical Synthesis and Highly Diastereoselective Diels—Alder Reactions of 1‐Alkylthio‐3‐silyloxybutadienes.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Chemistry; Service (business); Diels–Alder reaction; Combinatorial chemistry; Organic chemistry; Catalysis; Business; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004232636,0.0004614423,0.0006222141,0.00008028858,0.0001296202,0.00005895076,0.0003072215,0.0005031758,0.003808733],"category_scores_gemma":[0.003013695,0.000452568,0.000185174,0.0002676337,0.0002793939,0.0004464675,0.0001134604,0.0005636959,0.00002711096],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002396439,"about_ca_system_score_gemma":0.0002153548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003047457,"about_ca_topic_score_gemma":0.000001968543,"domain_scores_codex":[0.997553,3.097732e-7,0.0008883514,0.0004987021,0.0004588446,0.0006008203],"domain_scores_gemma":[0.9968504,0.001263519,0.0005506056,0.0007789936,0.0002072479,0.0003492745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001218433,0.0002506248,0.0000496569,0.0004415794,0.0001173832,0.00001336312,0.0008976462,6.286471e-8,0.4503146,0.0003476912,0.002256894,0.5451887],"study_design_scores_gemma":[0.0004704476,0.00002751539,0.0008734046,0.0001998872,0.0001396732,0.000299164,0.001142949,0.00001256805,0.9731002,0.000354081,0.02292109,0.0004589749],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.07497342,0.000164946,0.000003729974,0.000638621,0.00007312313,0.0001130509,0.00004293146,0.0001695907,0.9238206],"genre_scores_gemma":[0.9811091,0.0001708237,0.001325905,0.00009110313,0.0002423748,0.00004185771,0.0000206861,0.00004636303,0.01695177],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9068688,"threshold_uncertainty_score":0.9997926,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02215968909210025,"score_gpt":0.2900136853145526,"score_spread":0.2678539962224523,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}