{"id":"W2950316546","doi":"10.1002/chin.201104089","title":"ChemInform Abstract: A Novel Catalytic Decarbonylative Heck‐Type Reaction and Conjugate Addition of Aldehydes to Unsaturated Carbonyl Compounds.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Conjugate; Catalysis; Organic chemistry; Heck reaction; Medicinal chemistry; Combinatorial chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001654266,0.0003553928,0.0004104273,0.0001390628,0.0001357892,0.00009634448,0.0002228519,0.0003563417,0.0003334305],"category_scores_gemma":[0.0004766571,0.000370353,0.0001011054,0.000382802,0.00031867,0.0004517555,0.0001147527,0.0006352693,0.0000405617],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002177395,"about_ca_system_score_gemma":0.0002016279,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006096287,"about_ca_topic_score_gemma":0.0002438723,"domain_scores_codex":[0.9982347,5.527434e-9,0.0006402938,0.0003845801,0.0003439046,0.0003965535],"domain_scores_gemma":[0.9980475,0.0002166212,0.0004214662,0.000594838,0.0004348985,0.0002846298],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001382092,0.00008343838,0.00005221161,0.0001824612,0.00007500178,0.000002237543,0.001017861,6.08029e-7,0.9812446,0.00009151967,0.001230578,0.01588126],"study_design_scores_gemma":[0.0008603963,0.00002698054,0.002217017,0.0001262048,0.00008404173,0.0001251141,0.0006254684,0.0001330584,0.9889008,0.00004750129,0.006458397,0.0003949563],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8022827,0.00001680857,9.804786e-8,0.00006857884,0.0002321703,0.0001736637,0.0002653844,0.0001424858,0.1968181],"genre_scores_gemma":[0.9941359,0.00001339173,0.00003380259,0.00004177227,0.0001760044,0.00003437001,0.0009459299,0.0000443887,0.004574403],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1922437,"threshold_uncertainty_score":0.9998748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01494711627268845,"score_gpt":0.2605133426594201,"score_spread":0.2455662263867316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}