{"id":"W2950331595","doi":"10.1002/chin.201009060","title":"ChemInform Abstract: Enantio‐ and Diastereoselective Iodocyclopropanation of Allylic Alcohols by Using a Substituted Zinc Carbenoid.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Carbenoid; Allylic rearrangement; Zinc; Stereochemistry; Combinatorial chemistry; Organic chemistry; Catalysis; Rhodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001401611,0.0003356284,0.0003642355,0.0001076792,0.0001188486,0.00006168674,0.0002386024,0.0003743004,0.001331777],"category_scores_gemma":[0.0001582719,0.000335793,0.0001021758,0.0002127159,0.0001611977,0.0005227619,0.00009855066,0.0005197519,0.00001258187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001377581,"about_ca_system_score_gemma":0.0001477167,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001708765,"about_ca_topic_score_gemma":0.0001168309,"domain_scores_codex":[0.9982724,7.756894e-8,0.0005741936,0.0003449998,0.0003997927,0.0004085681],"domain_scores_gemma":[0.9985545,0.00006233214,0.0005010124,0.0004132177,0.0002775145,0.000191405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003208163,0.00003949431,0.0001592956,0.0002724681,0.00004389392,0.00000214874,0.0007806035,1.33241e-7,0.8282166,0.00008235766,0.000158594,0.1702124],"study_design_scores_gemma":[0.0008192567,0.00001112024,0.0004122608,0.00005256474,0.00006215696,0.00009576196,0.0006612059,0.00005114996,0.9845398,0.00004758506,0.01288235,0.0003648061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6934105,0.00008539722,0.00000165573,0.00001060819,0.00009048896,0.000160177,0.00007409115,0.0000915111,0.3060755],"genre_scores_gemma":[0.9964793,0.00004546812,0.0001942887,0.00001710839,0.0001246706,0.00003015795,0.0003311825,0.00004434323,0.002733467],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3033421,"threshold_uncertainty_score":0.9999094,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01303623007744357,"score_gpt":0.2444891004582912,"score_spread":0.2314528703808476,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}