{"id":"W2950376011","doi":"10.1002/chin.200942017","title":"ChemInform Abstract: TfNH<sub>2</sub> as Achiral Hydrogen‐Bond Donor Additive to Enhance the Selectivity of a Transition Metal Catalyzed Reaction. Highly Enantio‐ and Diastereoselective Rhodium‐Catalyzed Cyclopropanation of Alkenes Using α‐Cyano Diazoacetamide.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Rhodium; Catalysis; Transition metal; Selectivity; Combinatorial chemistry; Hydrogen; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001175412,0.0005216746,0.0001884766,0.0002081366,0.0001622378,0.0002243216,0.0003885759,0.0002673179,0.009517292],"category_scores_gemma":[0.0001174098,0.0001385062,0.0001347762,0.0001881251,0.0001589668,0.0003774907,0.0001738416,0.0004359735,0.002863987],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004396401,"about_ca_system_score_gemma":0.0002820567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001263537,"about_ca_topic_score_gemma":0.001565204,"domain_scores_codex":[0.9999298,0.000007286227,0.000004012241,0.00001943031,0.00001995146,0.00001953449],"domain_scores_gemma":[0.9999681,0.000005579538,0.000008959752,0.000003677846,0.000006428025,0.000007327019],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003376794,0.00005196462,0.00009000568,0.0002869528,0.00001370473,0.0002034097,0.00002730067,0.0001952145,0.9826503,0.001223534,0.003835898,0.011084],"study_design_scores_gemma":[0.00003665801,0.0001065914,0.0003122505,0.000008647674,0.00001274692,0.0002020009,0.000008294928,0.0004771279,0.9897222,0.00008280422,0.009024602,0.000006100388],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7972198,0.01187031,0.034648,0.002130753,0.001081755,0.0002267987,0.003504237,0.003457672,0.1458607],"genre_scores_gemma":[0.9537199,0.002697641,0.006795253,0.0003129098,0.00008412855,0.00004082049,0.001269307,0.0001916645,0.03488842],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009517292,"threshold_uncertainty_score":0.03183848,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008295179626023809,"score_gpt":0.2383845668401924,"score_spread":0.2300893872141686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}