{"id":"W2950437536","doi":"10.1002/chin.201106040","title":"ChemInform Abstract: Controlled and Chemoselective Reduction of Secondary Amides.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Reduction (mathematics); Transformation (genetics); Combinatorial chemistry; Organic chemistry; Chemoselectivity; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001448938,0.0003191416,0.0005656392,0.00004205758,0.00006666072,0.00001313412,0.0002412261,0.0002974894,0.01218232],"category_scores_gemma":[0.000241199,0.0003113466,0.0001411721,0.0001203288,0.0003326515,0.0003115737,0.0001100727,0.0003837102,0.00001640849],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001580894,"about_ca_system_score_gemma":0.0001489374,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002023956,"about_ca_topic_score_gemma":9.869478e-7,"domain_scores_codex":[0.998403,3.455957e-8,0.0006731296,0.0003226261,0.0002406677,0.0003606109],"domain_scores_gemma":[0.9986317,0.00007652721,0.0005063309,0.0004624291,0.000156589,0.0001664393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004754441,0.00009471078,0.00002185151,0.000491979,0.0001328461,0.000003595771,0.002338617,1.139344e-8,0.6862317,0.00008928167,0.001023272,0.3090966],"study_design_scores_gemma":[0.003038283,0.0000159154,0.0001071169,0.00007958558,0.00006229508,0.0001366706,0.002044491,0.000002798629,0.9916719,0.0006264688,0.001899937,0.0003145246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1491601,0.000215985,4.184012e-7,0.00001269075,0.00004972037,0.0001113518,0.00002101151,0.0001014017,0.8503273],"genre_scores_gemma":[0.9744292,0.00008321638,0.0001864445,0.00001590555,0.0001100427,0.00004216218,0.00003273354,0.00003962831,0.0250607],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.825269,"threshold_uncertainty_score":0.9999338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01072839413919683,"score_gpt":0.2166981606677004,"score_spread":0.2059697665285036,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}