{"id":"W2950439198","doi":"10.1055/s-2001-14589","title":"Allylsilane-Vinylcopper Reagents: Palladium-Mediated Coupling with Alkenyl Halides. Synthesis and Photochemical [2 + 2] Cyclization of (±)-Ipsdienol","year":2001,"lang":"en","type":"article","venue":"Synlett","topic":"Forest Insect Ecology and Management","field":"Environmental Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Junta de Castilla y León; University of British Columbia","keywords":"Chemistry; Halide; Reagent; Palladium; Bromide; Yield (engineering); Diene; Vinyl bromide; Photochemistry; Organic chemistry; Medicinal chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001925989,0.0001353918,0.0001694333,0.00004028724,0.0000822368,0.00001085285,0.0001407855,0.00009080779,0.001879441],"category_scores_gemma":[0.00009723208,0.000112436,0.00002335882,0.0001930159,0.0002698427,0.0001079939,0.0001093147,0.00007833695,0.0001162838],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006425007,"about_ca_system_score_gemma":0.000006374295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002476726,"about_ca_topic_score_gemma":0.0004347127,"domain_scores_codex":[0.999045,0.00002068455,0.0002004157,0.0002859697,0.0001999156,0.0002479994],"domain_scores_gemma":[0.9994967,0.0001093096,0.00009562909,0.0002096103,0.000009214812,0.00007952852],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"observational","study_design_gemma":"observational","study_design_scores_codex":[0.0005428909,0.0005883081,0.8074149,0.0001260952,0.0002591905,0.0002302519,0.0009755757,0.005577241,0.1696576,0.0003946224,0.01166565,0.002567603],"study_design_scores_gemma":[0.003065843,0.000719441,0.8745658,0.0003184543,0.0004258973,0.0002374879,0.0007643502,0.0229724,0.0684336,0.0005703637,0.02650359,0.001422752],"study_design_candidate":"observational","study_design_consensus":"observational","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924417,0.00003700456,0.0003657404,0.0002226336,0.00003845968,0.000312503,0.000004802218,0.00004470198,0.00653243],"genre_scores_gemma":[0.9986708,0.0001290025,0.0005054297,0.0003691976,0.00001427863,0.00005562406,0.00001623307,0.00001593467,0.0002235272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1012241,"threshold_uncertainty_score":0.999033,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006664388718708254,"score_gpt":0.1980917736857989,"score_spread":0.1914273849670906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}