{"id":"W2950439527","doi":"10.1002/chin.200909206","title":"ChemInform Abstract: Total Synthesis of (+)‐Cassaine via Transannular Diels—Alder Reaction.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Natural Compound Pharmacology Studies","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Diels–Alder reaction; Service (business); Combinatorial chemistry; Organic chemistry; Catalysis; Business; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001544098,0.0002037256,0.0002971999,0.0000156124,0.0001401137,0.00001459787,0.0002332249,0.0001598388,0.0009358755],"category_scores_gemma":[0.00006323372,0.00008521346,0.0001764156,0.0002419923,0.00009441128,0.0002731202,0.00003038093,0.0002057186,0.00002758849],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004839146,"about_ca_system_score_gemma":0.000007339567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004196297,"about_ca_topic_score_gemma":0.00001183347,"domain_scores_codex":[0.9989102,1.588417e-7,0.0003638246,0.0001844158,0.000228792,0.0003126095],"domain_scores_gemma":[0.9993226,0.0002378176,0.0001638476,0.00006752666,0.0001135506,0.0000946908],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000482364,0.00005938189,0.0000208443,0.00001155278,0.00002923657,0.000002604071,0.00007127935,7.911451e-8,0.4031129,0.00001873558,0.005589725,0.5910354],"study_design_scores_gemma":[0.0001787431,0.000136614,0.060369,0.000024324,0.00004862032,0.00003227227,0.000197953,0.000004267313,0.9039502,0.0002048806,0.03458361,0.0002695157],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6031303,0.0003381682,2.682498e-8,0.002123425,0.0001384994,0.0001972093,0.00003066859,0.00009850501,0.3939432],"genre_scores_gemma":[0.9957118,0.00008047823,0.00001305803,0.0002746421,0.0002001277,0.00001448758,0.00003232155,9.324178e-7,0.003672154],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.590766,"threshold_uncertainty_score":0.9999774,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01577975085874876,"score_gpt":0.2390315249995305,"score_spread":0.2232517741407818,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}