{"id":"W2950458711","doi":"10.1021/jo902706p","title":"Rhodium-Catalyzed Reductive Allylation of Conjugated Aldehydes with Allyl Acetate","year":2010,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Rhodium; Conjugated system; Catalysis; Chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002036193,0.0004852786,0.0002624369,0.0001895205,0.0001208785,0.0001967467,0.0003368784,0.0002224668,0.001294624],"category_scores_gemma":[0.0001803981,0.0001820884,0.0002438431,0.0001518228,0.0001729587,0.0002453756,0.000321099,0.000400545,0.0006721971],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003150237,"about_ca_system_score_gemma":0.0002524237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007331078,"about_ca_topic_score_gemma":0.002050984,"domain_scores_codex":[0.9998472,0.00001943386,0.00001083623,0.00002607113,0.00003209086,0.00006442299],"domain_scores_gemma":[0.999922,0.00001086856,0.00001700885,0.00001465851,0.00001388812,0.00002147881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007946345,0.00002622046,0.00009590928,0.00005186955,0.000009718731,0.00008208548,0.00003718025,0.0001643623,0.9959255,0.0003393813,0.00008410255,0.003104296],"study_design_scores_gemma":[0.00001045353,0.0000909887,0.0003115535,0.000002166759,0.000006717623,0.00008197527,0.000006053849,0.0003177881,0.9974741,0.00003489721,0.001658381,0.000004848333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9738988,0.002016225,0.01245481,0.0002175466,0.00009738354,0.0000824693,0.0002490136,0.0003601723,0.01062366],"genre_scores_gemma":[0.9912554,0.0007276366,0.003697542,0.00003043297,0.00001222708,0.00001705454,0.0001813082,0.00002804996,0.004050445],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001294624,"threshold_uncertainty_score":0.004330933,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005617645989339107,"score_gpt":0.2117448510140099,"score_spread":0.2061272050246707,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}