{"id":"W2950481893","doi":"10.1002/chin.201317032","title":"ChemInform Abstract: Chemoselective Nitration of Aromatic Sulfonamides with tert‐Butyl Nitrite.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre for Drug Research and Development","funders":"","keywords":"Nitration; Chemistry; Nitrite; Reagent; Organic chemistry; Combinatorial chemistry; Nitrate","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006874713,0.0002939342,0.0003667964,0.00005376826,0.00008904136,0.00006242325,0.0002487013,0.0002439482,0.00603513],"category_scores_gemma":[0.0001431234,0.0002224044,0.0001440774,0.000223089,0.0001734396,0.0005325195,0.00004258789,0.0002830275,0.0001209767],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001708217,"about_ca_system_score_gemma":0.00008202037,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002440943,"about_ca_topic_score_gemma":0.00001634072,"domain_scores_codex":[0.9984797,4.016445e-8,0.0005555737,0.0002352106,0.0003573037,0.0003721354],"domain_scores_gemma":[0.9986977,0.0002010499,0.0003734248,0.0003867263,0.0001772706,0.0001638565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003458987,0.0001828232,0.0004081834,0.0004410714,0.0001123515,0.000001032813,0.0003955622,1.393988e-7,0.7602947,0.00002659062,0.004071965,0.234031],"study_design_scores_gemma":[0.0004626454,0.00001852808,0.001880152,0.000178732,0.00004895704,0.00003166747,0.0006486275,0.00002945974,0.993028,0.0003014552,0.003059645,0.0003121004],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.404863,0.00003432041,3.171934e-7,0.00006619604,0.00001280804,0.0001157334,0.00001033823,0.00007614614,0.5948212],"genre_scores_gemma":[0.9858797,0.00002442558,0.0001231683,0.0000405117,0.0001122398,0.0001397917,0.0001162977,0.00003137007,0.01353255],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5812886,"threshold_uncertainty_score":0.9948735,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008458353378247685,"score_gpt":0.2043939409454798,"score_spread":0.1959355875672321,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}