{"id":"W2950493831","doi":"10.1002/chin.200950079","title":"ChemInform Abstract: γ‐Silylated α,β‐Unsaturated Amides — Preparation by [1,5]‐Sigmatropic Rearrangement and Use as Masked Dienolate Equivalents in Carbonyl Condensations.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Sigmatropic reaction; Combinatorial chemistry; Stereochemistry; Organic chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002480593,0.0007620368,0.0001919896,0.0004340741,0.0002556905,0.0002570594,0.0004587649,0.0003047161,0.01765433],"category_scores_gemma":[0.000180809,0.0002560196,0.0002104163,0.0003591157,0.0001902044,0.0006612867,0.0002621646,0.0007144895,0.006783131],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003304941,"about_ca_system_score_gemma":0.0005535432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003684848,"about_ca_topic_score_gemma":0.0006230213,"domain_scores_codex":[0.9998957,0.00001032383,0.00000744202,0.0000228928,0.00003810527,0.00002551009],"domain_scores_gemma":[0.9999375,0.000006935098,0.00001809362,0.00000778854,0.00001091929,0.0000187005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007383085,0.00009933137,0.000160668,0.0005825033,0.00003663248,0.0004160548,0.0001112724,0.0006437965,0.9411703,0.005178703,0.01127876,0.03958351],"study_design_scores_gemma":[0.00006968956,0.0004028022,0.0006006954,0.00002920914,0.00002172399,0.0003451938,0.00001978671,0.0003304384,0.9636404,0.0004232099,0.03409733,0.00001946067],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5384603,0.01938561,0.1132678,0.001918139,0.002529509,0.0005824422,0.01315148,0.003470167,0.3072347],"genre_scores_gemma":[0.8793764,0.01281523,0.02025131,0.0004849004,0.0002774755,0.0001596248,0.00808001,0.00052073,0.07803433],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01765433,"threshold_uncertainty_score":0.05905962,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01386637617592171,"score_gpt":0.248681158389948,"score_spread":0.2348147822140263,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}