{"id":"W2950539162","doi":"10.1002/chin.200437188","title":"The N‐Acyloxyiminium Ion Aza‐Prins Route to Octahydroindoles: Total Synthesis and Structural Confirmation of the Antithrombotic Marine Natural Product Oscillarin.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":103,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Natural product; Antithrombotic; Total synthesis; Prins reaction; Product (mathematics); Stereochemistry; Organic chemistry; Internal medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002927145,0.0002927283,0.0003090194,0.00002332238,0.0002586893,0.00008286217,0.0005268608,0.000120164,0.0001562424],"category_scores_gemma":[0.001431144,0.0001858004,0.0001190365,0.0002212956,0.0003243537,0.000133115,0.000523148,0.0003048313,0.000006659893],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002157009,"about_ca_system_score_gemma":0.000147422,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007763959,"about_ca_topic_score_gemma":0.00001887626,"domain_scores_codex":[0.9983661,0.00000272613,0.0005035161,0.0003309234,0.0004275012,0.0003692365],"domain_scores_gemma":[0.9983366,0.0002604707,0.0002831611,0.0009012524,0.0001083913,0.0001100924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000800408,0.00003093175,0.001209101,0.0004653264,0.0001200757,0.000001829755,0.001224504,0.00002230936,0.9221744,0.0002874152,0.0001182941,0.07426576],"study_design_scores_gemma":[0.0004144305,0.000007660634,0.00691855,0.0001323053,0.00007046759,0.0002082535,0.0005069207,0.00007253397,0.9906362,0.0001504798,0.0006424837,0.0002397347],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9703191,0.00008588728,0.000002905802,0.0009855354,0.00033639,0.0002161601,0.00002146198,0.00005935627,0.02797321],"genre_scores_gemma":[0.9973267,0.00002200276,0.0005535503,0.0000337999,0.0002122285,0.000018545,0.000009539226,0.00002861781,0.001794988],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07402603,"threshold_uncertainty_score":0.7576719,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00780071900544741,"score_gpt":0.2355281674041488,"score_spread":0.2277274483987014,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}