{"id":"W2950568246","doi":"10.1002/anie.201905540","title":"Direct Formic Acid Mediated<i>Z</i>‐Selective Reductive Coupling of Dienes and Aldehydes","year":2019,"lang":"en","type":"review","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Electrophile; Nucleophile; Reductive elimination; Formic acid; Isomerization; Olefin fiber; Catalysis; Triphos; Alkyl; Dissociation (chemistry); Hydroformylation; Ligand (biochemistry); Pincer ligand; Medicinal chemistry; Combinatorial chemistry; Photochemistry; Organic chemistry; Rhodium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003154106,0.0004430848,0.001067675,0.0002718588,0.00006537959,0.0000482314,0.000302577,0.0004302323,0.0009494663],"category_scores_gemma":[0.001005288,0.0004231829,0.0003600044,0.0002656601,0.0001700891,0.0003303836,0.0001513418,0.0003517501,0.00002872493],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004927894,"about_ca_system_score_gemma":0.0002691454,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003016636,"about_ca_topic_score_gemma":0.000004654657,"domain_scores_codex":[0.9977645,0.00001540829,0.0007690706,0.0006401767,0.0005925148,0.0002182784],"domain_scores_gemma":[0.997207,0.000904424,0.0009550479,0.0002865478,0.0005639175,0.00008301084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0007053842,0.001372538,0.0002740273,0.1094602,0.01286995,0.00005097777,0.001880977,0.0001394991,0.2347076,0.003279814,0.05286339,0.5823957],"study_design_scores_gemma":[0.0003773857,0.00002028618,0.000003342853,0.005207692,0.0006880906,0.00007239818,0.00007356249,0.00005245541,0.4080959,0.0002715034,0.584727,0.0004103455],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00006724019,0.9748992,0.001010284,0.00004388884,0.001863806,0.0002998002,0.001756547,0.0001027476,0.01995652],"genre_scores_gemma":[0.000904567,0.986028,0.0002856962,0.00002170847,0.001964371,0.0001793521,0.008815112,0.00008169733,0.001719555],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.5819853,"threshold_uncertainty_score":0.9999638,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0447145238998837,"score_gpt":0.3361989385724755,"score_spread":0.2914844146725918,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}