{"id":"W2950598402","doi":"10.1016/j.tetlet.2009.10.056","title":"Novel bulky pyrazolylphosphine ligands for the Suzuki coupling of aryl chlorides","year":2009,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Mount Saint Vincent University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Phenylboronic acid; Aryl; Suzuki reaction; Coupling (piping); Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002164235,0.0002342368,0.000279108,0.00005941102,0.0002144089,0.00006569947,0.0004013295,0.0001002699,0.00009775758],"category_scores_gemma":[0.0001614046,0.0001938009,0.0002343165,0.0001916044,0.0001938906,0.0001097189,0.00003094602,0.0002688199,0.00001015932],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001269745,"about_ca_system_score_gemma":0.00004241873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001614333,"about_ca_topic_score_gemma":0.00001503717,"domain_scores_codex":[0.998596,8.101753e-10,0.0004075712,0.0003304143,0.0002786836,0.0003873136],"domain_scores_gemma":[0.9985234,0.0005141693,0.0001953341,0.0006239627,0.00007193244,0.00007127144],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007188242,0.0001081451,0.0004448912,0.00005563545,0.00006328988,0.000002033727,0.0001841965,0.00333357,0.9937741,0.0002063864,0.001373112,0.0003827325],"study_design_scores_gemma":[0.0008604577,0.00002728966,0.002437591,0.00006223557,0.00009767098,0.00002300118,0.0001388977,0.007791982,0.9879743,0.00005729562,0.000311441,0.0002178611],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917671,0.0002490335,0.0005258031,0.006792648,0.00026652,0.0001624423,0.0000757701,0.0001535591,0.000007121102],"genre_scores_gemma":[0.9984905,0.00002913528,0.00001709742,0.0006936361,0.0004510735,0.00002647865,0.00005370343,0.00003917175,0.0001992591],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006723342,"threshold_uncertainty_score":0.7902972,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01674334423658577,"score_gpt":0.2625423675276338,"score_spread":0.2457990232910481,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}