{"id":"W2950607598","doi":"10.1039/c9cc02194a","title":"The mechanism of structural changes and crystallization kinetics of amorphous red phosphorus to black phosphorus under high pressure","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"2D Materials and Applications","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; National Key Research and Development Program of China; Collaborative Innovation Center of Suzhou Nano Science and Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions; Canada Foundation for Innovation","keywords":"Phosphorus; Kinetics; Crystallization; Amorphous solid; Black phosphorus; Mechanism (biology); Chemistry; High pressure; Materials science; Chemical engineering; Crystallography; Thermodynamics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001312177,0.0002080259,0.0001805404,0.0001989131,0.0002665633,0.0002711763,0.0003130623,0.0002184163,0.001177557],"category_scores_gemma":[0.0003460978,0.0002258416,0.0002127264,0.0001620628,0.0004729157,0.0003951335,0.0001871916,0.0004508327,0.0001770077],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002776252,"about_ca_system_score_gemma":0.0002627211,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0017054,"about_ca_topic_score_gemma":0.0009368472,"domain_scores_codex":[0.9998794,0.000009678927,0.000004505972,0.00002700677,0.00005249938,0.00002690792],"domain_scores_gemma":[0.9998904,0.00004701405,0.00002060095,0.0000108892,0.00002197894,0.000009075736],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007102582,0.00001783311,0.0003904904,0.00007597369,0.000005989075,0.0002178677,0.00009338945,0.0004930631,0.9949262,0.001058432,0.0001065455,0.00254326],"study_design_scores_gemma":[0.000007521149,0.0000472425,0.002620524,0.000002502844,0.00000327661,0.0001246805,0.0000299854,0.003626539,0.9925936,0.0002541015,0.0006826088,0.000007288163],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912511,0.0008666065,0.004237299,0.000120427,0.0000221821,0.00003362153,0.0002253267,0.0001032095,0.00314013],"genre_scores_gemma":[0.9974844,0.0004045307,0.001032327,0.00001138067,0.000005448149,0.0000191005,0.00006765724,0.00001688555,0.0009582079],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0017054,"threshold_uncertainty_score":0.003939271,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0161896573138219,"score_gpt":0.2510094960851749,"score_spread":0.234819838771353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}