{"id":"W2950607598","doi":"10.1039/c9cc02194a","title":"The mechanism of structural changes and crystallization kinetics of amorphous red phosphorus to black phosphorus under high pressure","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"2D Materials and Applications","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; National Key Research and Development Program of China; Collaborative Innovation Center of Suzhou Nano Science and Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions; Canada Foundation for Innovation","keywords":"Phosphorus; Kinetics; Crystallization; Amorphous solid; Black phosphorus; Mechanism (biology); Chemistry; High pressure; Materials science; Chemical engineering; Crystallography; Thermodynamics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001283101,0.0001064291,0.0001942747,0.00001945355,0.0000943401,0.00004008576,0.0007632492,0.00007479206,0.00007316159],"category_scores_gemma":[0.00005234686,0.00008237089,0.00002418744,0.0001529441,0.0002784531,0.00003969135,0.0005256657,0.0000654044,0.00001101551],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001622625,"about_ca_system_score_gemma":0.00001536628,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001295496,"about_ca_topic_score_gemma":0.00002180864,"domain_scores_codex":[0.9992068,0.00004678078,0.000290142,0.0001705356,0.0001368104,0.0001488806],"domain_scores_gemma":[0.998159,0.0001873823,0.0001974049,0.001224467,0.0001724411,0.00005933675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001780119,0.00002696232,0.00001904498,0.00002119127,0.000008045608,1.087658e-8,0.0001666372,0.00003847695,0.9131672,0.08626426,0.0001134319,0.0001569226],"study_design_scores_gemma":[0.0001680005,0.0000397532,0.0006274956,0.00002579666,0.00003367356,0.000001030823,0.0001360501,0.0003075615,0.9829717,0.01266586,0.002928159,0.0000948723],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953249,0.0006610578,0.0005266489,0.002482802,0.00007101816,0.0004865946,0.0001329903,0.00003104782,0.000282954],"genre_scores_gemma":[0.9937261,0.0003848771,0.005573774,0.00006836922,0.00001370342,0.00004952934,0.00004035223,0.00001566919,0.0001275993],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0735984,"threshold_uncertainty_score":0.3358988,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0161896573138219,"score_gpt":0.2510094960851749,"score_spread":0.234819838771353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}