{"id":"W2950622525","doi":"10.1139/cjc-2012-0399","title":"Highly efficient iron phthalocyanine catalyzed oxidative synthesis of imines from alcohols and amines","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Nucleophile; Lewis acids and bases; Organic chemistry; Oxidative coupling of methane; Oxidative phosphorylation; Phthalocyanine; Base (topology); Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009094286,0.0001775016,0.0003816387,0.000121607,0.00005923644,0.00004362583,0.000289523,0.000134481,0.002865514],"category_scores_gemma":[0.0005663471,0.0001607415,0.0001290265,0.0002254153,0.0001647469,0.0000916006,0.00002074179,0.0001546001,0.000009761879],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001177837,"about_ca_system_score_gemma":0.0002507046,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00500705,"about_ca_topic_score_gemma":0.0001721897,"domain_scores_codex":[0.9988579,0.00001049046,0.0005031907,0.0001730697,0.0002343362,0.000220993],"domain_scores_gemma":[0.9981472,0.000200173,0.0004881957,0.0002337277,0.0003371298,0.0005935936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001053107,0.00003528174,0.004138004,0.0001103866,0.0002033908,0.00004776955,0.0003683751,0.00005840222,0.9898675,0.000002272382,0.0008444489,0.004313615],"study_design_scores_gemma":[0.0003725201,0.000004279494,0.001165178,0.00009842182,0.0001158406,0.0000690576,0.000875294,0.0001261933,0.9965749,0.00001927153,0.0004168678,0.0001621479],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925451,0.00106789,0.00001546533,0.000266792,0.00003340505,0.00002765489,0.0001672415,0.000005481768,0.005871029],"genre_scores_gemma":[0.999079,0.00002544269,0.0001454977,0.00001936707,0.0001485227,0.000005564636,0.00004277284,0.00001842259,0.0005153873],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006707404,"threshold_uncertainty_score":0.998046,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006798369815230004,"score_gpt":0.1951343270131092,"score_spread":0.1883359571978792,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}