{"id":"W2950627197","doi":"10.1021/jo701606u","title":"The Cycloaddition of Nitrones with Homochiral Cyclopropanes","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Cyclopropane; Cycloaddition; Adduct; Chemistry; Nitrone; Ring (chemistry); Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000676092,0.0001858072,0.0002380208,0.00001950835,0.000220096,0.00002442828,0.0005588735,0.0001036769,0.0009602782],"category_scores_gemma":[0.0001280019,0.00009551783,0.0001081838,0.0001806241,0.0002151441,0.00008842905,0.00005695894,0.0005491128,0.000006219031],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001329783,"about_ca_system_score_gemma":0.0001577059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006778258,"about_ca_topic_score_gemma":0.00001185949,"domain_scores_codex":[0.9984421,0.00001737713,0.0005908506,0.00009932768,0.000577985,0.0002724174],"domain_scores_gemma":[0.9978446,0.0003327069,0.0009634316,0.0004230288,0.0003443607,0.00009190795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004345205,0.00005176535,0.0001718338,0.0001006971,0.00009383873,0.00002098479,0.0003541087,0.000006179662,0.9954315,0.00001065679,0.0001123988,0.003211479],"study_design_scores_gemma":[0.0005950092,0.00004811637,0.0002549781,0.0001028158,0.0001461618,0.002743415,0.006403264,0.000002005835,0.9873033,0.0002471084,0.002032002,0.0001218413],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915254,0.0007774041,0.0006598258,0.0002148219,0.00009218706,0.00003945397,0.00000533742,0.00002363526,0.006661942],"genre_scores_gemma":[0.9980059,0.0002786033,0.0002501931,0.00001153375,0.0005859003,7.848124e-7,0.000004156502,0.00003564919,0.0008273136],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008128255,"threshold_uncertainty_score":0.999953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004170575861907701,"score_gpt":0.1972854133153959,"score_spread":0.1931148374534882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}