{"id":"W2950645760","doi":"10.1002/chin.200249004","title":"ChemInform Abstract: Bis(trichlorophosphine)iminium Salts, [Cl<sub>3</sub>P=N=PCl<sub>3</sub>]<sup>+</sup>, with Transition Metal Halide Counter‐Ions.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Iminium; Halide; Transition metal; Ion; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000119378,0.0008220127,0.0002865594,0.0002813401,0.0003640267,0.0004076831,0.0006291515,0.0003755501,0.0209364],"category_scores_gemma":[0.0002559154,0.0002530403,0.0001531208,0.0004239023,0.0001739751,0.0006602439,0.0003776313,0.0006154918,0.009105976],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000504137,"about_ca_system_score_gemma":0.0004352516,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008673354,"about_ca_topic_score_gemma":0.0009208109,"domain_scores_codex":[0.9998564,0.00001609068,0.000009196005,0.00003020786,0.00007133829,0.0000167124],"domain_scores_gemma":[0.9999332,0.00001124087,0.00001967269,0.000007360801,0.00001318821,0.00001519484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001116151,0.00006984938,0.0001909409,0.0009297127,0.00003868265,0.0002756231,0.0000978025,0.0003539057,0.9478152,0.002052351,0.02063244,0.02642747],"study_design_scores_gemma":[0.00008955807,0.0001980597,0.0003645301,0.00001527913,0.0000225235,0.0002603681,0.00002029685,0.0004098164,0.9507942,0.0002323376,0.04758262,0.0000104266],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.5247461,0.01655601,0.04080603,0.002794657,0.00221364,0.0005759677,0.008122343,0.01012131,0.394064],"genre_scores_gemma":[0.7933529,0.006905203,0.009075581,0.0004884677,0.0002725794,0.0001921847,0.005421618,0.001022035,0.1832694],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.0209364,"threshold_uncertainty_score":0.07003921,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01242647135497599,"score_gpt":0.1919488762692649,"score_spread":0.1795224049142889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}