{"id":"W2950661726","doi":"10.1002/chin.200820040","title":"ChemInform Abstract: A Convergent Synthesis of Polysubstituted Aromatic Nitriles via Palladium‐Catalyzed C—H Functionalization.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Surface modification; Palladium; Combinatorial chemistry; Catalysis; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002629826,0.0004001301,0.0005622781,0.0001986873,0.0002036095,0.00002371429,0.0003803924,0.0002987555,0.02958997],"category_scores_gemma":[0.001213847,0.0004092891,0.0003080567,0.0005788693,0.0003344101,0.0004031462,0.0001015396,0.0001840173,0.000244185],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003130704,"about_ca_system_score_gemma":0.0004023252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007565231,"about_ca_topic_score_gemma":0.000004493889,"domain_scores_codex":[0.9972226,2.300371e-7,0.001203718,0.0003617953,0.0008191401,0.0003924946],"domain_scores_gemma":[0.997529,0.0004692841,0.0007023275,0.0007201271,0.0003278272,0.0002513756],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001003964,0.00143518,0.005026898,0.005585293,0.002186084,0.00007115554,0.003446105,0.0001450086,0.5831015,0.001873328,0.1571938,0.2389317],"study_design_scores_gemma":[0.0008790695,0.000005817388,0.001838616,0.0001307467,0.0001377098,0.0002133799,0.0002093089,0.0002472504,0.964406,0.0001751249,0.03129033,0.0004666798],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.0714353,0.0003578939,0.000316162,0.0001255122,0.0005062438,0.0003068487,0.0002017894,0.0004339248,0.9263163],"genre_scores_gemma":[0.9340479,0.0002142357,0.0008085052,0.0001385809,0.0004580677,0.000246688,0.002289919,0.00009660238,0.06169948],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8646169,"threshold_uncertainty_score":0.9998359,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0233630555787157,"score_gpt":0.2460525899229923,"score_spread":0.2226895343442766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}