{"id":"W2950686178","doi":"10.1021/acs.langmuir.9b01238","title":"Electric-Field-Driven Molecular Recognition Reactions of Guanine with 1,2-Dipalmitoyl-<i>sn</i>-<i>glycero</i>-3-cytidine Monolayers Deposited on Gold Electrodes","year":2019,"lang":"en","type":"article","venue":"Langmuir","topic":"Lipid Membrane Structure and Behavior","field":"Biochemistry, Genetics and Molecular Biology","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada; Ministerio de Ciencia y Tecnología; Ministerio de Economía y Competitividad","keywords":"Chemistry; Moiety; Guanine; Cytosine; Crystallography; Monolayer; Electric field; Cytidine; Stereochemistry; Nucleotide; Organic chemistry; DNA","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001568828,0.0003701614,0.0002006943,0.00009043894,0.0001033243,0.0001918505,0.0002909165,0.0002061762,0.0006546695],"category_scores_gemma":[0.000238016,0.0001505015,0.0001596694,0.0001193577,0.0001612655,0.0001637517,0.0001302973,0.0003213808,0.000136749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002495576,"about_ca_system_score_gemma":0.0001430911,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00103525,"about_ca_topic_score_gemma":0.00153297,"domain_scores_codex":[0.9998956,0.00002020286,0.00000665221,0.00002565599,0.00002386701,0.00002810261],"domain_scores_gemma":[0.9999006,0.00004006995,0.00002037777,0.000006240932,0.00001682513,0.00001589049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004486078,0.000005995303,0.00005258118,0.00001472519,0.000002751186,0.00001785123,0.00001386742,0.00003515945,0.9994346,0.00002516226,0.000006841172,0.000345553],"study_design_scores_gemma":[0.000005477976,0.000068961,0.0007216823,0.000001718964,0.00000358282,0.00002257725,0.00001218166,0.0005630212,0.9984066,0.00001186265,0.0001800609,0.000002343132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979962,0.0002867653,0.001135595,0.00002224996,0.00001231281,0.00001356699,0.00005276421,0.00002443023,0.0004561846],"genre_scores_gemma":[0.9959406,0.0004090845,0.002514904,0.00002543187,0.000006695293,0.0000183616,0.0001264406,0.00001170515,0.0009468501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00103525,"threshold_uncertainty_score":0.002190053,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005393063734364137,"score_gpt":0.2169295441737502,"score_spread":0.211536480439386,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}