{"id":"W2950686563","doi":"10.1002/chin.201507330","title":"ChemInform Abstract: Application of Cyclic Phosphonamide Reagents in the Total Synthesis of Natural Products and Biologically Active Molecules","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Xenon Pharmaceuticals (Canada)","funders":"","keywords":"Chemistry; Reagent; Combinatorial chemistry; Organic chemistry; Molecule; Natural (archaeology); Total synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004861322,0.0002128088,0.0003363165,0.00002912018,0.00001994854,0.00001069421,0.0004044947,0.0001971917,0.00007458951],"category_scores_gemma":[0.002423129,0.0001545156,0.00006121626,0.0002176821,0.0002634094,0.0001057052,0.0001294683,0.0002300927,0.000003073438],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001041579,"about_ca_system_score_gemma":0.00009181177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006184504,"about_ca_topic_score_gemma":0.00000145594,"domain_scores_codex":[0.9986559,3.910783e-7,0.0005325404,0.0002655576,0.0003178989,0.0002277629],"domain_scores_gemma":[0.9984398,0.0004081594,0.0004210655,0.0005301444,0.0001360992,0.00006472121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000102813,0.000082346,0.00010287,0.0002642415,0.00002579631,0.000001222563,0.001076018,1.701517e-7,0.6504502,0.00002325203,0.0001192745,0.3477518],"study_design_scores_gemma":[0.0003275049,0.000009252654,0.003204364,0.0000663579,0.00002754236,0.00004369926,0.002536122,0.00002242199,0.9930972,0.0001172117,0.0003864192,0.0001618518],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7459734,0.0001791742,4.189856e-7,0.00009976932,0.0000222663,0.0001409912,0.00002909864,0.00002239169,0.2535325],"genre_scores_gemma":[0.9987556,0.00002951802,0.0003916263,0.00001344559,0.00004476486,0.00006307309,0.00003630817,0.00001377937,0.0006519],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.34759,"threshold_uncertainty_score":0.6300964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01796791746796961,"score_gpt":0.263297817322209,"score_spread":0.2453298998542394,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}