{"id":"W2950718625","doi":"10.1002/chin.201112145","title":"ChemInform Abstract: NHC‐Catalyzed Intramolecular Redox Amidation for the Synthesis of Functionalized Lactams.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Chemistry; Intramolecular force; Catalysis; Ring (chemistry); Amine gas treating; Redox; Combinatorial chemistry; Base (topology); Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002442377,0.000586497,0.0001794102,0.0004197751,0.0002741529,0.0003149129,0.000620958,0.0003898336,0.01286845],"category_scores_gemma":[0.0002075917,0.0001924384,0.0001437936,0.0002666123,0.0001839094,0.0004235105,0.0003948885,0.0007417119,0.003320215],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006409492,"about_ca_system_score_gemma":0.0005364663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006373042,"about_ca_topic_score_gemma":0.001361084,"domain_scores_codex":[0.9998391,0.0000181348,0.000008292176,0.00003234364,0.00006565501,0.00003636618],"domain_scores_gemma":[0.9999553,0.000008976915,0.000009416945,0.000006434371,0.000008241247,0.00001163378],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008335591,0.0002656436,0.000289341,0.0009465571,0.000045193,0.000492649,0.000086586,0.001209746,0.8548265,0.0109275,0.0237176,0.1063593],"study_design_scores_gemma":[0.000130295,0.0003442283,0.0006123068,0.00003705647,0.00003123718,0.0004853122,0.00001403379,0.002264838,0.9507877,0.0004812825,0.04479115,0.00002048913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4892813,0.02779351,0.1158183,0.003481027,0.002210683,0.001099724,0.006070863,0.006324224,0.3479204],"genre_scores_gemma":[0.9449027,0.0062813,0.01476572,0.0003589089,0.0001704421,0.0001437103,0.002260607,0.0001503214,0.03096636],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01286845,"threshold_uncertainty_score":0.04304922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01544523743622975,"score_gpt":0.2215578570206409,"score_spread":0.2061126195844112,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}