{"id":"W2950752832","doi":"10.1021/ol0155541","title":"Unnatural Natural Products from the Transannular Cyclization of Lathyrane Diterpenes","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Public Health Agency of Canada","keywords":"Chemistry; Diterpene; Natural product; Reactivity (psychology); Terpene; Stereochemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001118714,0.0003392301,0.0001307383,0.0002436592,0.0001338526,0.0003094114,0.000143916,0.0001751562,0.002119781],"category_scores_gemma":[0.0001474486,0.0001241455,0.0001817429,0.0001963477,0.0002572724,0.0003066995,0.00029815,0.0004087297,0.0006983675],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001340362,"about_ca_system_score_gemma":0.0001738182,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001457947,"about_ca_topic_score_gemma":0.0006066395,"domain_scores_codex":[0.9999403,0.00001167965,0.000005818118,0.000008976745,0.0000118513,0.0000214764],"domain_scores_gemma":[0.9999275,0.00001096773,0.00001736079,0.00001676413,0.000007483665,0.00001983236],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001365936,0.00001897272,0.0002071277,0.00006827898,0.000008175786,0.000531948,0.00007393935,0.0003707061,0.9900524,0.001846119,0.00007380381,0.006612038],"study_design_scores_gemma":[0.00001988951,0.0003288638,0.001622452,0.0000119534,0.00001573553,0.0005622436,0.00005494717,0.0002236343,0.9860008,0.0008390678,0.01030723,0.00001317665],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9791908,0.002333371,0.007428542,0.0001853703,0.00005625207,0.00004198493,0.000435631,0.0000984006,0.01022972],"genre_scores_gemma":[0.9890106,0.002209498,0.003361419,0.00007787064,0.00002149014,0.00002561444,0.0005955055,0.00003179753,0.00466622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002119781,"threshold_uncertainty_score":0.007091343,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004610841282827667,"score_gpt":0.1983583015924903,"score_spread":0.1937474603096627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}