{"id":"W2950752832","doi":"10.1021/ol0155541","title":"Unnatural Natural Products from the Transannular Cyclization of Lathyrane Diterpenes","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Public Health Agency of Canada","keywords":"Chemistry; Diterpene; Natural product; Reactivity (psychology); Terpene; Stereochemistry; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009164885,0.0001372714,0.0001164746,0.0000170405,0.00005913816,0.0000156206,0.0002571277,0.00006576806,0.00005391951],"category_scores_gemma":[0.00009617701,0.00009152531,0.00005603231,0.0001837327,0.00007081218,0.000008496088,0.00005423364,0.0001244525,0.00000574621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007251809,"about_ca_system_score_gemma":0.00001927611,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005874213,"about_ca_topic_score_gemma":0.00005073241,"domain_scores_codex":[0.9991741,0.00005192851,0.0001612336,0.000302688,0.0001377972,0.0001722199],"domain_scores_gemma":[0.9994392,0.00001343027,0.00007412719,0.0003834701,0.00006735721,0.00002236708],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006725688,0.00001558752,0.001946322,0.000007696324,0.00004275536,0.000003318803,0.00007239424,0.00000622291,0.990498,0.000008722151,0.005284458,0.002047277],"study_design_scores_gemma":[0.0004276402,0.00004587404,0.02224517,0.00000968734,0.00003443635,0.00001969933,0.00001866767,0.0000183095,0.9506001,0.00001620826,0.02639323,0.0001710082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9776399,0.002566595,0.00007605211,0.01905906,0.0004460418,0.0001627436,0.00001739589,0.0000127896,0.00001939758],"genre_scores_gemma":[0.9957972,0.0004012239,0.0001264526,0.002376271,0.0006400726,0.000002068043,0.0004687621,0.00001619626,0.0001717646],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03989793,"threshold_uncertainty_score":0.3732294,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004610841282827667,"score_gpt":0.1983583015924903,"score_spread":0.1937474603096627,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}