{"id":"W2950754769","doi":"10.1016/j.tet.2004.08.006","title":"The effect of vicinyl olefinic halogens on cross-coupling reactions using Pd(0) catalysis","year":2004,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Negishi coupling; Halogen; Sonogashira coupling; Oxidative addition; Halide; Iodide; Catalysis; Bromide; Bromine; Coupling reaction; Olefin fiber; Chlorine; Medicinal chemistry; Chloride; Organic chemistry; Palladium; Combinatorial chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000254963,0.0002512489,0.0002714338,0.00004910661,0.0004856538,0.00005411776,0.0002876831,0.0001663075,0.0002730036],"category_scores_gemma":[0.0004630434,0.000196415,0.0002187508,0.0003189067,0.0002457131,0.00007004107,0.00005437832,0.0004254743,0.00007813602],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005294441,"about_ca_system_score_gemma":0.00009027682,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003356055,"about_ca_topic_score_gemma":0.00004680385,"domain_scores_codex":[0.9985635,0.000009906613,0.0004146198,0.0003601562,0.0003093093,0.0003425036],"domain_scores_gemma":[0.9981735,0.0006002018,0.0002625146,0.0008034236,0.00007346546,0.00008686381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005045009,0.00006754244,0.004496661,0.0000824764,0.0001251358,0.000005008166,0.00005388397,0.006930775,0.9877831,0.00005614314,0.000009045674,0.0003397808],"study_design_scores_gemma":[0.000723491,0.00006278409,0.0008202505,0.0001253329,0.0001436892,0.0000332506,0.00009306672,0.0003709926,0.9968912,0.0000656979,0.0004876301,0.0001826397],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915696,0.000119802,0.00006100647,0.00008264712,0.0001232112,0.00007327963,0.00003107562,0.0001159179,0.00782345],"genre_scores_gemma":[0.9989151,0.00002228996,0.00006991451,0.000005480089,0.0001584035,0.00001224671,0.00003237126,0.00004847051,0.0007357054],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009108077,"threshold_uncertainty_score":0.8009573,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01435127042485958,"score_gpt":0.2966598861723902,"score_spread":0.2823086157475306,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}