{"id":"W2950775883","doi":"10.1021/ol035977y","title":"Exploration of Ionic Liquids as Soluble Supports for Organic Synthesis. Demonstration with a Suzuki Coupling Reaction","year":2003,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":156,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ionic liquid; Methanol; Suzuki reaction; Aqueous medium; Ammonia; Ionic bonding; Cleavage (geology); Aqueous solution; Organic chemistry; Combinatorial chemistry; Coupling reaction; Palladium; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002987543,0.0002334742,0.0002708366,0.00009553067,0.0002298911,0.00007735919,0.0001219404,0.0001547411,0.0006190027],"category_scores_gemma":[0.0004458188,0.0002407756,0.00009391534,0.0002917231,0.00009965916,0.0006061565,0.00001423426,0.0001907244,0.00004244151],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003764999,"about_ca_system_score_gemma":0.0003575197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005436223,"about_ca_topic_score_gemma":0.0001106207,"domain_scores_codex":[0.9984981,0.000001103354,0.0004473233,0.0004250069,0.0002928766,0.0003356099],"domain_scores_gemma":[0.998677,0.0002572733,0.0003397611,0.0004824874,0.0001586512,0.00008480696],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007579532,0.0000996829,0.0003991804,0.000108104,0.00007486432,0.000004477103,0.0002430581,0.0002037777,0.9981593,0.0002344358,0.0003382906,0.00005895482],"study_design_scores_gemma":[0.0006055951,0.0000519574,0.00003826967,0.00009400424,0.0001944169,0.0001133418,0.0006399364,0.0004663371,0.9971372,0.0001026382,0.0002935285,0.0002627124],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903758,0.00002105832,0.007976606,0.0009210326,0.0001977826,0.0002463963,0.00000866635,0.0001540589,0.00009865467],"genre_scores_gemma":[0.9990612,0.00001811108,0.0002103983,0.00009200757,0.0001120971,0.0001006637,0.0001102302,0.00008844003,0.0002068975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00868541,"threshold_uncertainty_score":0.9818544,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01479207307956389,"score_gpt":0.2412594351568567,"score_spread":0.2264673620772928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}