{"id":"W2950777146","doi":"10.1002/chin.200716081","title":"Copper‐Catalyzed Amidation of Allylic and Benzylic C—H Bonds.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Allylic rearrangement; Copper; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002907859,0.0007069831,0.0004541944,0.0004015302,0.0003413019,0.0002439421,0.0008945539,0.0003755112,0.007649316],"category_scores_gemma":[0.0004705092,0.0002306483,0.0002933477,0.0004424801,0.0002756281,0.0005132895,0.0005812792,0.0008660321,0.002147018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004491735,"about_ca_system_score_gemma":0.0005172394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009113429,"about_ca_topic_score_gemma":0.002302031,"domain_scores_codex":[0.9996864,0.00003930547,0.00001485518,0.00004755921,0.00006003236,0.0001518414],"domain_scores_gemma":[0.9998988,0.00001657441,0.00002119123,0.0000188533,0.00001547589,0.00002902532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00137507,0.0003315882,0.0005287561,0.001619931,0.0002259637,0.001234552,0.0003662445,0.001153501,0.8723359,0.009012,0.0199674,0.09184913],"study_design_scores_gemma":[0.0001437341,0.0007088257,0.0009041415,0.0000673105,0.00005515219,0.0006014512,0.00006636846,0.001197484,0.9690893,0.0009880608,0.0261474,0.00003084137],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7367675,0.02089705,0.05652469,0.001125286,0.00249275,0.0005723325,0.002587143,0.001720075,0.1773131],"genre_scores_gemma":[0.9683439,0.006307133,0.005806653,0.0001563268,0.00009720381,0.0000770573,0.0008797589,0.00007719484,0.01825492],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007649316,"threshold_uncertainty_score":0.02558947,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01214557091457502,"score_gpt":0.2393687332321243,"score_spread":0.2272231623175493,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}