{"id":"W2950777146","doi":"10.1002/chin.200716081","title":"Copper‐Catalyzed Amidation of Allylic and Benzylic C—H Bonds.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Chemistry; Allylic rearrangement; Copper; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001478882,0.00009483275,0.0001408915,0.00004014629,0.00003993898,0.00001346715,0.00009151565,0.0000955028,0.0003933693],"category_scores_gemma":[0.00008448218,0.00008882386,0.00004255938,0.00008024773,0.00007015927,0.0001214969,0.00003415326,0.00006758331,0.00002029501],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003984475,"about_ca_system_score_gemma":0.00002320482,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003974047,"about_ca_topic_score_gemma":0.000007545649,"domain_scores_codex":[0.9993189,5.891223e-8,0.0002681087,0.000117244,0.0001381997,0.0001575119],"domain_scores_gemma":[0.9994264,0.00008739268,0.0001234042,0.0002441692,0.0000431417,0.00007547806],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001936503,0.00004879422,0.00118864,0.0001429611,0.00004060102,0.000001271564,0.0004275571,8.653151e-8,0.6453313,0.0004983839,0.001908433,0.3503927],"study_design_scores_gemma":[0.0002339842,0.000004093775,0.001590139,0.00002721524,0.00002390248,0.00002111487,0.0006687253,0.000008727287,0.9799902,0.00004191588,0.01729069,0.00009929564],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5292849,0.00009661468,0.000001891447,0.00002678626,0.00001505475,0.00002267079,0.000007470872,0.0000273928,0.4705172],"genre_scores_gemma":[0.9956849,0.00003979735,0.00003377526,0.00001911905,0.00006440462,0.000005055827,0.00009114831,0.0000100642,0.004051741],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4664655,"threshold_uncertainty_score":0.4307118,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01214557091457502,"score_gpt":0.2393687332321243,"score_spread":0.2272231623175493,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}