{"id":"W2950794470","doi":"10.1021/jo015610b","title":"Intramolecular 1,3-Dipolar Cycloadditions of Norbornadiene-Tethered Nitrones","year":2001,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Intramolecular force; Norbornadiene; Chemistry; Stereoselectivity; Stereochemistry; Cycloaddition; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002399468,0.0004897124,0.0002903598,0.0002536628,0.0002413034,0.0002613151,0.0004781507,0.0002580059,0.002510174],"category_scores_gemma":[0.0002586344,0.0002420269,0.0002686034,0.0002476021,0.0002386088,0.0003891831,0.0002633412,0.0008512387,0.0006374023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003863603,"about_ca_system_score_gemma":0.0003847048,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004891791,"about_ca_topic_score_gemma":0.002593918,"domain_scores_codex":[0.9998254,0.00002289067,0.00001391268,0.00004073044,0.00004237998,0.00005466325],"domain_scores_gemma":[0.9998963,0.00002754137,0.00002685536,0.00001416509,0.00001462429,0.00002053201],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001144504,0.00007305938,0.0000995438,0.0001535025,0.00001296141,0.0003484988,0.00009822536,0.0006391903,0.9891122,0.00153743,0.0001488898,0.007662069],"study_design_scores_gemma":[0.00001771851,0.0002677655,0.0004378083,0.000008089449,0.0000115593,0.0002116319,0.00002041853,0.0003504404,0.9948131,0.0001100513,0.003741335,0.00001028568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9404895,0.004541915,0.03196262,0.0001987358,0.0001596135,0.0002520005,0.0005152752,0.0002263157,0.02165392],"genre_scores_gemma":[0.9775574,0.003816606,0.009850699,0.0000578919,0.00002688926,0.00008383112,0.0003122472,0.00004304463,0.008251286],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002510174,"threshold_uncertainty_score":0.008397341,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04042771374758585,"score_gpt":0.3564530011457599,"score_spread":0.316025287398174,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}