{"id":"W2950815170","doi":"10.1002/ijch.201100082","title":"[2.2]Paracyclophane‐Derived Planar‐Chiral Hydrogen‐Bond Receptors","year":2012,"lang":"en","type":"article","venue":"Israel Journal of Chemistry","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Enantiopure drug; Chemistry; Thiourea; Hydrogen bond; Tetramethylammonium; Combinatorial chemistry; Catalysis; Organic chemistry; Enantioselective synthesis; Molecule; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003874171,0.0002957409,0.0004912388,0.00003682806,0.0001097718,0.00005839043,0.0005944098,0.0002074898,0.002924818],"category_scores_gemma":[0.0002090447,0.0002461948,0.000347438,0.0000803297,0.0001106241,0.0003334603,0.00006502532,0.0004387526,0.00005707905],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001164113,"about_ca_system_score_gemma":0.00009961483,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000776903,"about_ca_topic_score_gemma":2.6008e-7,"domain_scores_codex":[0.9979668,0.00001881189,0.0008115933,0.0001576932,0.0005309926,0.0005140759],"domain_scores_gemma":[0.9982564,0.0001715883,0.000667571,0.0003797454,0.0001109137,0.0004137241],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001659957,0.0002139901,0.005324219,0.0001854692,0.000219111,0.00002721036,0.0004241294,0.000004565568,0.9810354,0.000007580998,0.007726218,0.00466608],"study_design_scores_gemma":[0.0006236808,0.00001906398,0.0001544091,0.0002030555,0.00008703578,0.0009078544,0.0007561935,0.000008256846,0.9447584,0.0001688707,0.05200822,0.0003050088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9144294,0.003388515,0.000009039243,0.0002319027,0.0003154973,0.00001951967,0.000007075915,0.00003293322,0.08156608],"genre_scores_gemma":[0.9937442,0.000124706,0.001098993,0.00009806469,0.001699465,0.000002947979,0.000007640491,0.00004402694,0.003179976],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07931475,"threshold_uncertainty_score":0.999999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01528839333083485,"score_gpt":0.2254702522420645,"score_spread":0.2101818589112296,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}