{"id":"W2950825806","doi":"10.1002/chin.201504205","title":"ChemInform Abstract: On the Hydrostannylation of Aryl Propargylic Alcohols and Their Derivatives: Remarkable Differences in Both Regio‐ and Stereoselectivity in Radical‐ and Nonradical‐Mediated Transformations.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Aryl; Stereoselectivity; Library science; Stereochemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004929176,0.001060728,0.0002858156,0.0006822944,0.0004102908,0.0006096372,0.0007265897,0.0006190514,0.03354312],"category_scores_gemma":[0.0003017854,0.0002551835,0.0002183409,0.0007032017,0.0004862732,0.0006956599,0.0006975104,0.001234046,0.00998637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005622861,"about_ca_system_score_gemma":0.0006272269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000650841,"about_ca_topic_score_gemma":0.001328254,"domain_scores_codex":[0.9997565,0.00002345044,0.00001077899,0.00005140898,0.0001070963,0.00005077285],"domain_scores_gemma":[0.9999013,0.00002683319,0.00001889741,0.00001478494,0.0000230384,0.00001514502],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001537375,0.0003929029,0.0003431333,0.001926537,0.00008851809,0.0006516587,0.0002100322,0.001699569,0.6284313,0.03319791,0.04054264,0.2909783],"study_design_scores_gemma":[0.0001246942,0.0005215833,0.0006648306,0.00006248785,0.00008536525,0.0006191013,0.00002757018,0.0007523079,0.9102976,0.00150801,0.08529997,0.00003651213],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3030128,0.03667087,0.05220633,0.003981408,0.002054795,0.0004833557,0.005283409,0.004303182,0.5920039],"genre_scores_gemma":[0.8185344,0.03675673,0.01730736,0.001320817,0.0006434955,0.0001509307,0.00523133,0.0005309468,0.119524],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.03354312,"threshold_uncertainty_score":0.1122129,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0315039040700397,"score_gpt":0.247468983889344,"score_spread":0.2159650798193043,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}