{"id":"W2950829650","doi":"10.1002/chin.200451112","title":"Investigations of α‐Siloxy—Epoxide Ring Expansions Forming 1‐Azaspirocyclic Ketones.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Epoxide; Ring (chemistry); Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009276543,0.0001782104,0.0002757212,0.0001350211,0.0001326962,0.00001885559,0.0002796032,0.0001371509,0.0002149668],"category_scores_gemma":[0.0003862192,0.0001707531,0.0001951707,0.0004627692,0.0001110223,0.0002522684,0.0001039873,0.0001412356,0.00003641569],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000144282,"about_ca_system_score_gemma":0.0001003726,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001672779,"about_ca_topic_score_gemma":0.00001544152,"domain_scores_codex":[0.9987467,1.606076e-7,0.0004890914,0.000197852,0.0002812431,0.0002849684],"domain_scores_gemma":[0.9989663,0.00009703142,0.0002379448,0.0004770127,0.00006458972,0.0001571286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000127248,0.0002086349,0.00247692,0.0004818008,0.0002170505,0.000008432744,0.00289316,0.00006466034,0.322954,0.003826806,0.0006278791,0.6662279],"study_design_scores_gemma":[0.0003619512,0.000004648328,0.0002873214,0.0001325356,0.00006652358,0.00001163357,0.001485782,0.00001970382,0.9928352,0.0006444936,0.003952628,0.0001976131],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3647756,0.0002230682,0.00004879147,0.00008885201,0.00002951019,0.00004175829,0.00001435889,0.00008789951,0.6346901],"genre_scores_gemma":[0.9964938,0.00004024717,0.0008799756,0.00005527442,0.00008121641,0.00003705614,0.00004791755,0.00002315217,0.002341354],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6698812,"threshold_uncertainty_score":0.6963111,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01834067653105951,"score_gpt":0.2337670440812625,"score_spread":0.215426367550203,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}