{"id":"W2950844477","doi":"10.1002/chin.200732263","title":"Polyyne Synthesis Using Carbene—Carbenoid Rearrangements","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Carbenoid; Carbene; Combinatorial chemistry; Organic chemistry; Catalysis; Rhodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002336468,0.000595673,0.0002825546,0.0003594519,0.0004698114,0.0005768638,0.0005306534,0.0004246129,0.005756648],"category_scores_gemma":[0.0002967086,0.0002412919,0.0003391542,0.0003943524,0.0003960193,0.000804187,0.0007032687,0.00112603,0.001521092],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007234094,"about_ca_system_score_gemma":0.0006995088,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008370047,"about_ca_topic_score_gemma":0.001839564,"domain_scores_codex":[0.9997866,0.00001868728,0.00001743406,0.0000651388,0.00004466139,0.00006756691],"domain_scores_gemma":[0.9999141,0.00002212231,0.00001326781,0.00002193406,0.00001042037,0.00001833899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000448904,0.0002557743,0.0003058217,0.001161712,0.00008943577,0.001910338,0.000389227,0.004077416,0.8582144,0.05441825,0.008119677,0.07060909],"study_design_scores_gemma":[0.000124213,0.0004611305,0.0005635438,0.00004608904,0.00003565465,0.0006261977,0.00003907887,0.001972305,0.9534467,0.002850539,0.03978881,0.00004568648],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6602162,0.01368348,0.0844063,0.002053152,0.002386478,0.0009100614,0.001599207,0.001383492,0.2333616],"genre_scores_gemma":[0.9632891,0.005097801,0.01350914,0.0001484772,0.00006238821,0.0001242572,0.0003876631,0.00009579343,0.01728534],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005756648,"threshold_uncertainty_score":0.0192579,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02118170147026736,"score_gpt":0.2586498656293239,"score_spread":0.2374681641590566,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}