{"id":"W2950878099","doi":"10.1021/ol802010n","title":"A Versatile Cascade of Intramolecular Vilsmeier−Haack and Azomethine Ylide 1,3-Dipolar Cycloaddition toward Tricyclic Cores of Alkaloids","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Intramolecular force; Azomethine ylide; Citation; Cycloaddition; Computer science; Chemistry; Library science; Stereochemistry; 1,3-Dipolar cycloaddition; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001019917,0.0002924249,0.0005095997,0.00008365224,0.00007056398,0.000007638017,0.0002990275,0.0002106744,0.001764381],"category_scores_gemma":[0.0004634963,0.0003097055,0.0001195211,0.0003165993,0.0004811873,0.0001181421,0.0001280175,0.000350822,0.00001120004],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000143122,"about_ca_system_score_gemma":0.00007986693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005595634,"about_ca_topic_score_gemma":0.000002018652,"domain_scores_codex":[0.9982145,0.00002786026,0.000564398,0.0004308197,0.0004242483,0.0003381061],"domain_scores_gemma":[0.9986769,0.0002085671,0.0003648818,0.0005502637,0.00006062663,0.0001387393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004974701,0.00007787664,0.0004979362,0.0002772104,0.0001052031,0.00006791553,0.001133053,0.000005107675,0.9962506,0.000009973235,0.0008660798,0.0006592898],"study_design_scores_gemma":[0.001158675,0.00002805347,0.0005937748,0.0000926708,0.00008842099,0.0002661406,0.0002690725,0.00002745392,0.9965512,0.00008212742,0.0005646038,0.0002777668],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964823,0.000505816,0.001542832,0.0007673787,0.00005404755,0.00008303091,0.0001095401,0.00007266266,0.0003824545],"genre_scores_gemma":[0.9973246,0.0002838893,0.001810306,0.000290249,0.0001077837,0.000006374613,0.00005460487,0.00006825183,0.00005396083],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001753181,"threshold_uncertainty_score":0.9999355,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009164575441437265,"score_gpt":0.2096616106116827,"score_spread":0.2004970351702454,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}