{"id":"W2950914375","doi":"10.1002/chin.201117059","title":"ChemInform Abstract: Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Desymmetrization; Hydroacylation; Enantioselective synthesis; Stereochemistry; Organic chemistry; Aldehyde; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002109625,0.0007190158,0.0002195017,0.00042591,0.0002269622,0.0003186256,0.0004632291,0.0002976274,0.01141442],"category_scores_gemma":[0.0002301062,0.0002167576,0.0001950282,0.0003207799,0.0003049852,0.0004961721,0.0004632913,0.0007224087,0.003339536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003830784,"about_ca_system_score_gemma":0.000576395,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006593798,"about_ca_topic_score_gemma":0.001075872,"domain_scores_codex":[0.9998516,0.00001376302,0.00000825093,0.00002878084,0.00004166172,0.00005595515],"domain_scores_gemma":[0.9999177,0.00001359856,0.00002517692,0.00001359263,0.0000129886,0.00001692841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001070072,0.0001747129,0.0005799023,0.0007707724,0.00006026583,0.00120918,0.000214259,0.001366833,0.9138597,0.01467803,0.01233283,0.05368337],"study_design_scores_gemma":[0.0001074367,0.000241659,0.0008436298,0.00003042716,0.00002703129,0.000602763,0.00002916434,0.0006158419,0.9686199,0.0005097432,0.02834824,0.00002424801],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7406586,0.005983814,0.04976242,0.001872049,0.0009888295,0.0005490593,0.00626968,0.002815252,0.1911004],"genre_scores_gemma":[0.9637769,0.003744751,0.008321331,0.0002030087,0.00007395165,0.00007811715,0.001931731,0.0001625217,0.02170765],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01141442,"threshold_uncertainty_score":0.038185,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01867817958243225,"score_gpt":0.2192777746853231,"score_spread":0.2005995951028909,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}