{"id":"W2950922268","doi":"10.1071/en19095","title":"Emergent functional behaviour of humic substances perceived as complex labile aggregates of small organic molecules and oligomers","year":2019,"lang":"en","type":"article","venue":"Environmental Chemistry","topic":"Marine and coastal ecosystems","field":"Earth and Planetary Sciences","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; Compute Canada","keywords":"Chemistry; Stacking; Pollutant; Environmental chemistry; Non-covalent interactions; Sorption; Humic acid; Molecule; Hydrophobic effect; Organic chemistry; Adsorption; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001638419,0.0002335098,0.0001936881,0.0003011499,0.0001900007,0.0004168706,0.0001637792,0.0002672363,0.0007344843],"category_scores_gemma":[0.0003143585,0.0001166193,0.0003098055,0.0001391887,0.0003917422,0.0003917481,0.000248316,0.0002312137,0.00009334262],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003261968,"about_ca_system_score_gemma":0.0001884586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00130939,"about_ca_topic_score_gemma":0.0007901558,"domain_scores_codex":[0.9999454,0.00001042242,0.000001978329,0.0000134635,0.00001205629,0.00001664337],"domain_scores_gemma":[0.9998581,0.00005321064,0.00003064355,0.000008918038,0.00002398394,0.00002509316],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00021487,0.0001196848,0.01052268,0.0002485925,0.0001190887,0.0005898275,0.000383391,0.2482733,0.7201927,0.01162408,0.0004744367,0.007237343],"study_design_scores_gemma":[0.0000109198,0.0001191083,0.00812713,0.000008974383,0.00001885405,0.00009145041,0.0001279653,0.9351186,0.05177115,0.003986008,0.0005912622,0.00002862462],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837938,0.0001615729,0.014555,0.0000456145,0.000007611899,0.00001673283,0.0001121468,0.00006166347,0.001245792],"genre_scores_gemma":[0.9975588,0.0001111407,0.001727268,0.0000197309,0.000003646163,0.00001424354,0.00007615387,0.00001330714,0.0004757235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00130939,"threshold_uncertainty_score":0.002603531,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007056670927700679,"score_gpt":0.1610401887277542,"score_spread":0.1539835178000535,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}