{"id":"W2950930252","doi":"10.1002/chin.200531066","title":"An Efficient Synthesis of Propargylamines via C—H Activation Catalyzed by Copper(I) in Ionic Liquids.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":124,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Copper; Ionic liquid; Ionic bonding; Combinatorial chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002864754,0.0001688387,0.0002320573,0.00009657886,0.00003866866,0.00001674501,0.0002050521,0.000148354,0.001189086],"category_scores_gemma":[0.0004318761,0.0001692577,0.00006115194,0.0002900167,0.00007644482,0.0002071411,0.00003856446,0.0001041409,0.00002259259],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003161566,"about_ca_system_score_gemma":0.000102264,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005580107,"about_ca_topic_score_gemma":0.000009852911,"domain_scores_codex":[0.9987519,0.000001318838,0.0004958524,0.0002381984,0.0003025873,0.0002101378],"domain_scores_gemma":[0.9989802,0.0001998428,0.0002126886,0.0004073367,0.0001195183,0.00008042136],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001042709,0.0002896282,0.0001755184,0.000185456,0.00001746355,2.75951e-7,0.0003687088,0.000507294,0.8840205,0.00005970179,0.001392518,0.1128787],"study_design_scores_gemma":[0.000438297,0.000006569238,0.0001136129,0.00007272696,0.00001493505,0.000005151961,0.0001323633,0.006687752,0.9891303,0.000007054737,0.003210313,0.0001808851],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9101733,0.00009307554,0.000538755,0.0002170147,0.00005651026,0.0001946866,0.00005071986,0.0001248397,0.0885511],"genre_scores_gemma":[0.9969581,0.000007648932,0.0005639143,0.00003005057,0.0001051764,0.00008205126,0.0004023332,0.0000238812,0.001826869],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1126978,"threshold_uncertainty_score":0.999724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01090496903128209,"score_gpt":0.2625028931889293,"score_spread":0.2515979241576472,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}