{"id":"W2950977640","doi":"10.1002/chin.201511101","title":"ChemInform Abstract: Palladium‐Catalyzed Carbonylation of Halo Arene‐cis‐dihydrodiols to the Corresponding Carboxylates. Access to Compounds Unavailable by Toluene Dioxygenase‐Mediated Dihydroxylation of the Corresponding Benzoate Esters.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Toluene; Carbonylation; Palladium; Dihydroxylation; Catalysis; Organic chemistry; Medicinal chemistry; Enantioselective synthesis; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001412403,0.0006396844,0.0008296988,0.0003567819,0.0002365027,0.0002311247,0.002068659,0.000336422,0.0003694568],"category_scores_gemma":[0.001600016,0.0004927682,0.0002730189,0.002000712,0.0001387111,0.0008829743,0.0007712496,0.0004448599,0.00008777107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000756553,"about_ca_system_score_gemma":0.0003746854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003612016,"about_ca_topic_score_gemma":0.0001207494,"domain_scores_codex":[0.9953245,0.000003025307,0.001743651,0.000618042,0.001523222,0.0007875497],"domain_scores_gemma":[0.9951755,0.0004731317,0.001486796,0.001627552,0.0006682562,0.0005688113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007457924,0.0001082387,0.0009367518,0.000343977,0.0001928757,0.000003134356,0.00468151,0.001074824,0.9657968,0.00007445758,0.01870661,0.007335075],"study_design_scores_gemma":[0.001304828,0.00003820855,0.0009283911,0.0002254855,0.0001003813,0.00001227501,0.000669346,0.001494927,0.987732,0.00004359838,0.00688892,0.0005616661],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9131997,0.0001219109,0.00001789625,0.0003731466,0.000603756,0.0009770888,0.0005110519,0.0001349528,0.08406048],"genre_scores_gemma":[0.9910394,0.00001450702,0.00005318078,0.0002063632,0.0001532866,0.0001615839,0.001475232,0.00009115777,0.006805264],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0778397,"threshold_uncertainty_score":0.9997524,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03183282359631701,"score_gpt":0.2635351891885306,"score_spread":0.2317023655922136,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}