{"id":"W2950986527","doi":"10.1002/chin.200715137","title":"Palladium‐Catalyzed Oxidative Activation of Arylcyclopropanes.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Catalysis; Oxidative phosphorylation; Palladium; Combinatorial chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001578115,0.00018186,0.0002152368,0.00008511365,0.00004933299,0.00001089922,0.0001950497,0.0001760373,0.001568742],"category_scores_gemma":[0.0001240115,0.0001773572,0.00009689455,0.0002073412,0.00006535965,0.0002296614,0.00005809398,0.0001846594,0.00005964264],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001645048,"about_ca_system_score_gemma":0.00006308305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002794323,"about_ca_topic_score_gemma":0.00001436682,"domain_scores_codex":[0.9987699,1.598862e-7,0.0004187962,0.000200217,0.0003282056,0.0002827414],"domain_scores_gemma":[0.9989495,0.0000881595,0.0003172461,0.0003670151,0.0001726673,0.0001053851],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008762351,0.00003712893,0.00008911415,0.0002004598,0.00002684755,0.000002414283,0.001022854,4.125254e-7,0.8383968,0.0001911933,0.0001416809,0.1598034],"study_design_scores_gemma":[0.0005206763,0.000009573242,0.0002662232,0.0000547153,0.00001666501,0.0000140075,0.002279516,0.000003549197,0.9802251,0.0001061461,0.01631362,0.0001901839],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4002116,0.00002160752,0.0001060135,0.00001514885,0.00005485226,0.00008070953,0.000009240519,0.0001091149,0.5993917],"genre_scores_gemma":[0.9945289,0.00001673606,0.0003921295,0.00002158701,0.0001399769,0.00001142932,0.0002637749,0.00002676189,0.004598656],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.594793,"threshold_uncertainty_score":0.9993439,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01280995039079493,"score_gpt":0.2414526967274642,"score_spread":0.2286427463366693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}