{"id":"W2950996043","doi":"10.1002/chin.200722060","title":"Design of a Conformationally Rigid Hydrazide Organic Catalyst.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Hydrazide; Catalysis; Combinatorial chemistry; Click chemistry; Organic chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000177168,0.0001157886,0.0001649268,0.00003463565,0.00004786875,0.00001067322,0.000176396,0.0001333203,0.002834701],"category_scores_gemma":[0.0001343047,0.00009902695,0.00007940504,0.0001200777,0.00007107566,0.0001180921,0.00003799509,0.0001198856,0.00009618798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009479631,"about_ca_system_score_gemma":0.00006727421,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002014828,"about_ca_topic_score_gemma":0.000002893141,"domain_scores_codex":[0.9990706,8.968237e-8,0.0004074052,0.00009581793,0.0002110564,0.0002149824],"domain_scores_gemma":[0.999177,0.0002243366,0.000177599,0.0002328679,0.00008803702,0.0001002068],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002810553,0.00003848876,0.00002263471,0.00009107709,0.00004306023,0.000001537124,0.0002346165,0.000001081867,0.9415174,0.00008991959,0.001719456,0.05621259],"study_design_scores_gemma":[0.0002131398,0.000003626546,0.00003607733,0.00003393699,0.00002125169,0.00002565928,0.0001718845,0.0000798051,0.9779576,0.000106352,0.02122737,0.0001233166],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.04365976,0.00006410908,0.0009276812,0.00004531325,0.0000372027,0.00005982742,0.00001223037,0.00008195014,0.9551119],"genre_scores_gemma":[0.9912899,0.00002115497,0.0006333144,0.00004846778,0.00009523339,0.00000351867,0.00008182739,0.00001461502,0.007811945],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9476302,"threshold_uncertainty_score":0.9980769,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01244321585392578,"score_gpt":0.2246457851590682,"score_spread":0.2122025693051424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}