{"id":"W2951028868","doi":"10.1002/chin.199918099","title":"ChemInform Abstract: Intermolecular Carbenoid Insertions: Reactions of 2-Substituted Thiophenes with Ethyl Diazoacetate in the Presence of Rhodium(II) Acetate.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Carbenoid; Chemistry; Ethyl diazoacetate; Rhodium; Intermolecular force; Medicinal chemistry; Organic chemistry; Catalysis; Cyclopropanation; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000308471,0.0007705289,0.0002680215,0.0002379143,0.0002611189,0.0002758245,0.000816008,0.000515205,0.006519302],"category_scores_gemma":[0.0002592425,0.0002497863,0.0002658427,0.000303215,0.0003055225,0.0006770261,0.000546029,0.0008244,0.002004991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002519068,"about_ca_system_score_gemma":0.0002672389,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004621631,"about_ca_topic_score_gemma":0.000817141,"domain_scores_codex":[0.9997986,0.00003263033,0.000007649191,0.00003681618,0.0000606376,0.00006369231],"domain_scores_gemma":[0.9999341,0.00002022729,0.00001602721,0.00001261103,0.000006286943,0.00001078117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0006242888,0.0001778648,0.0002352457,0.0009210838,0.0001083622,0.001111564,0.0004140832,0.0006771077,0.9562311,0.006621907,0.004832345,0.028045],"study_design_scores_gemma":[0.00008404384,0.0006280337,0.000639345,0.00002530163,0.00003526848,0.000854235,0.00004648425,0.0008003716,0.9816806,0.0003534472,0.01482511,0.00002781903],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.8583826,0.01036349,0.03473076,0.0008202199,0.0007350215,0.0003644279,0.0008621445,0.001109767,0.09263162],"genre_scores_gemma":[0.9731026,0.005010299,0.004878778,0.0001351,0.00008366911,0.00007132295,0.000560576,0.00009249093,0.01606516],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.006519302,"threshold_uncertainty_score":0.02180916,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01180141762679892,"score_gpt":0.236128839634541,"score_spread":0.2243274220077421,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}