{"id":"W2951054851","doi":"10.1002/chin.201210142","title":"ChemInform Abstract: Synthesis of 6H‐Dibenzo[b,d]pyran‐6‐ones Using the Inverse Electron Demand Diels—Alder Reaction.","year":2012,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis of Organic Compounds","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Pyran; Inverse; Diels–Alder reaction; Electron; Organic chemistry; Computational chemistry; Medicinal chemistry; Catalysis; Mathematics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005984746,0.0003118386,0.000501813,0.0001278758,0.0001461947,0.00002293911,0.0002597675,0.000227169,0.0009599831],"category_scores_gemma":[0.0007096265,0.0002248092,0.0002394951,0.0002833284,0.0001978291,0.0005693341,0.00009997033,0.000319563,0.00006894138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003237444,"about_ca_system_score_gemma":0.0001795238,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008735863,"about_ca_topic_score_gemma":0.00001136194,"domain_scores_codex":[0.9980804,3.04956e-7,0.0006102439,0.0001882586,0.0005004776,0.0006203501],"domain_scores_gemma":[0.9980984,0.0004244913,0.0003779726,0.0007226204,0.0001474115,0.0002291347],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000521508,0.0005781143,0.004578892,0.0009260182,0.0007580062,0.000006085271,0.004356389,4.560405e-7,0.678581,0.0001521723,0.04362214,0.2659192],"study_design_scores_gemma":[0.0004469512,0.00002803023,0.01277232,0.0001865037,0.00040512,0.0002365063,0.001189504,0.0000195559,0.9501798,0.00001909318,0.03427354,0.0002430314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5566846,0.0005869266,7.759914e-7,0.0005118548,0.0002233883,0.0003532972,0.000005511843,0.00009432802,0.4415393],"genre_scores_gemma":[0.9945395,0.0001224641,0.0001245966,0.000211931,0.0005175542,0.00002717728,0.00001043733,0.00004949028,0.004396851],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4378549,"threshold_uncertainty_score":0.9999533,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02608512173830094,"score_gpt":0.2700599647807445,"score_spread":0.2439748430424436,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}